| Literature DB >> 15863927 |
Yumiko Yamano1, Masayoshi Ito.
Abstract
A synthesis of optically active vomifoliol stereoisomers 1-4 and their glucosides, roseoside stereoisomers 5-8, was accomplished via alpha-acetylenic alcohol 11a or 11b effectively prepared by an asymmetric transfer hydrogenation of alpha,beta-acetylenic ketone 10. Simultaneous separation of these stereoisomers by HPLC was also performed.Entities:
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Year: 2005 PMID: 15863927 DOI: 10.1248/cpb.53.541
Source DB: PubMed Journal: Chem Pharm Bull (Tokyo) ISSN: 0009-2363 Impact factor: 1.645