Literature DB >> 15756318

Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution.

Chivukula V Sastri1, Mi Sook Seo, Mi Joo Park, Kwan Mook Kim, Wonwoo Nam.   

Abstract

A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species.

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Year:  2005        PMID： 15756318     DOI： 10.1039/b415507f

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  13 in total

1.  Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand.

Authors:  Anna Company; Irene Prat; Jonathan R Frisch; Ruben Mas-Ballesté; Mireia Güell; Gergely Juhász; Xavi Ribas; Eckard Münck; Josep M Luis; Lawrence Que; Miquel Costas
Journal:  Chemistry       Date:  2011-01-05       Impact factor: 5.236

2.  Epoxidation Catalyzed by the Nonheme Iron(II)- and 2-Oxoglutarate-Dependent Oxygenase, AsqJ: Mechanistic Elucidation of Oxygen Atom Transfer by a Ferryl Intermediate.

Authors:  Jikun Li; Hsuan-Jen Liao; Yijie Tang; Jhih-Liang Huang; Lide Cha; Te-Sheng Lin; Justin L Lee; Igor V Kurnikov; Maria G Kurnikova; Wei-Chen Chang; Nei-Li Chan; Yisong Guo
Journal:  J Am Chem Soc       Date:  2020-03-16       Impact factor: 15.419

3.  [Fe(IV)═O(TBC)(CH3CN)]2+: comparative reactivity of iron(IV)-oxo species with constrained equatorial cyclam ligation.

Authors:  Samuel A Wilson; Junying Chen; Seungwoo Hong; Yong-Min Lee; Martin Clémancey; Ricardo Garcia-Serres; Takashi Nomura; Takashi Ogura; Jean-Marc Latour; Britt Hedman; Keith O Hodgson; Wonwoo Nam; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2012-07-06       Impact factor: 15.419

Review 4.  Oxidation of alkane and alkene moieties with biologically inspired nonheme iron catalysts and hydrogen peroxide: from free radicals to stereoselective transformations.

Authors:  Giorgio Olivo; Olaf Cussó; Margarida Borrell; Miquel Costas
Journal:  J Biol Inorg Chem       Date:  2017-01-25       Impact factor: 3.358

5.  Inhibition of the purified 20S proteasome by non-heme iron complexes.

Authors:  Jai Prakash; Sara M Schmitt; Q Ping Dou; Jeremy J Kodanko
Journal:  Metallomics       Date:  2011-12-15       Impact factor: 4.526

6.  Mechanism of S-oxygenation by a cysteine dioxygenase model complex.

Authors:  Devesh Kumar; G Narahari Sastry; David P Goldberg; Sam P de Visser
Journal:  J Phys Chem A       Date:  2011-12-12       Impact factor: 2.781

7.  Near-stoichiometric conversion of H(2)O(2) to Fe(IV)=O at a nonheme iron(II) center. Insights into the O-O bond cleavage step.

Authors:  Feifei Li; Jason England; Lawrence Que
Journal:  J Am Chem Soc       Date:  2010-02-24       Impact factor: 15.419

8.  Theoretical study of cyclohexane hydroxylation by three possible isomers of [FeIV(O)(R-TPEN)] 2+: does the pentadentate ligand wrapping around the metal center differently lead to the different stability and reactivity?

Authors:  Yi Wang; Yong Wang; Keli Han
Journal:  J Biol Inorg Chem       Date:  2009-01-27       Impact factor: 3.358

9.  What factors influence the reactivity of C-H hydroxylation and C=C epoxidation by [Fe(IV)(L(ax))(1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane)(O)](n+).

Authors:  Wang Yi; Liu Yuan; Yang Kun; He Zhengwen; Tian Jing; Fei Xu; Guo Hong; Wang Yong
Journal:  J Biol Inorg Chem       Date:  2015-09-07       Impact factor: 3.358

10.  Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity.

Authors:  Andrea Decker; Jan-Uwe Rohde; Eric J Klinker; Shaun D Wong; Lawrence Que; Edward I Solomon
Journal:  J Am Chem Soc       Date:  2007-12-05       Impact factor: 15.419
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