Literature DB >> 15755141

Imidazo[1,5-a]pyridine: a versatile architecture for stable N-heterocyclic carbenes.

Manuel Alcarazo1, Stephen J Roseblade, Andrew R Cowley, Rosario Fernández, John M Brown, José M Lassaletta.   

Abstract

The imidazo[1,5-a]pyridine skeleton provides a versatile platform for the generation of new types of stable N-heterocyclic carbenes. Rh(I) mono- (6) and biscarbenes (7) from imidazo[1,5-a]pyridin-3-ylidenes (ImPy) and derivatives such as 13 from a mesoionic carbene were synthesized and characterized.

Entities:  

Year:  2005        PMID： 15755141     DOI： 10.1021/ja0423769

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  17 in total

1.  Carbon Dioxide Cleavage by a Ni2 Complex Supported by a Binucleating Bis(N-Heterocyclic Carbene) Framework.

Authors:  Emily Y Tsui; Theodor Agapie
Journal:  Polyhedron       Date:  2014-07-02       Impact factor: 3.052

2.  A rigid cyclic (alkyl)(amino)carbene ligand leads to isolation of low-coordinate transition-metal complexes.

Authors:  Vincent Lavallo; Yves Canac; Alan DeHope; Bruno Donnadieu; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2005-11-11       Impact factor: 15.336

Review 3.  Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes.

Authors:  Darrin M Flanigan; Fedor Romanov-Michailidis; Nicholas A White; Tomislav Rovis
Journal:  Chem Rev       Date:  2015-05-20       Impact factor: 60.622

4.  One-pot synthesis of highly substituted N-fused heteroaromatic bicycles from azole aldehydes.

Authors:  Victor K Outlaw; Felipe B d'Andrea; Craig A Townsend
Journal:  Org Lett       Date:  2015-03-27       Impact factor: 6.005

Review 5.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

6.  Palladium-Catalyzed Highly Regioselective C-3 Arylation of Imidazo[1,5-a]pyridine.

Authors:  Chunhui Huang; Alexandros Giokaris; Vladimir Gevorgyan
Journal:  Chem Lett       Date:  2011       Impact factor: 1.389

7.  Synthesis of Chiral Bifunctional NHC Ligands and Survey of Their Utilities in Asymmetric Gold Catalysis.

Authors:  Jun-Qi Zhang; Yunkui Liu; Xing-Wang Wang; Liming Zhang
Journal:  Organometallics       Date:  2019-10-28       Impact factor: 3.876

8.  Synthesis and isolation of a stable, axially-chiral seven-membered N-heterocyclic carbene.

Authors:  Christopher C Scarborough; Ilia A Guzei; Shannon S Stahl
Journal:  Dalton Trans       Date:  2009-02-13       Impact factor: 4.390

9.  Isolation of a C5-deprotonated imidazolium, a crystalline "abnormal" N-heterocyclic carbene.

Authors:  Eugenia Aldeco-Perez; Amos J Rosenthal; Bruno Donnadieu; Pattiyil Parameswaran; Gernot Frenking; Guy Bertrand
Journal:  Science       Date:  2009-10-23       Impact factor: 47.728

10.  Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes.

Authors:  Glenn Kuchenbeiser; Bruno Donnadieu; Guy Bertrand
Journal:  J Organomet Chem       Date:  2008-03-01       Impact factor: 2.369
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