Literature DB >> 19255609

Stable Bis(diisopropylamino)cyclopropenylidene (BAC) as Ligand for Transition Metal Complexes.

Glenn Kuchenbeiser1, Bruno Donnadieu, Guy Bertrand.   

Abstract

Several nickel(0), palladium(II), and rhodium(I) complexes have been prepared using for the first time the stable bis(diisopropylamino)cyclopropenylidene (BAC). Based on single crystal X-ray diffraction studies and spectroscopic data, the structural and electronic properties of these complexes are discussed. Moreover, their similarities and differences with the analogous NHC complexes are emphasized.

Entities:  

Year:  2008        PMID： 19255609      PMCID： PMC2405893          DOI： 10.1016/j.jorganchem.2007.11.056

Source DB:  PubMed          Journal:  J Organomet Chem        ISSN： 0022-328X            Impact factor:   2.369


  26 in total

1.  Stable Carbenes.

Authors:  Didier Bourissou; Olivier Guerret; François P. Gabbaï; Guy Bertrand
Journal:  Chem Rev       Date:  2000-01-12       Impact factor: 60.622

2.  CO fixation to stable acyclic and cyclic alkyl amino carbenes: stable amino ketenes with a small HOMO-LUMO gap.

Authors:  Vincent Lavallo; Yves Canac; Bruno Donnadieu; Wolfgang W Schoeller; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2006-05-19       Impact factor: 15.336

3.  N-heterocyclic carbenes as organocatalysts.

Authors:  Nicolas Marion; Silvia Díez-González; Steven P Nolan
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

4.  Carbene activation of P4 and subsequent derivatization.

Authors:  Jason D Masuda; Wolfgang W Schoeller; Bruno Donnadieu; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336

5.  A stable chiral diaminocyclopropenylidene.

Authors:  Dirk Holschumacher; Cristian G Hrib; Peter G Jones; Matthias Tamm
Journal:  Chem Commun (Camb)       Date:  2007-06-25       Impact factor: 6.222

6.  A methylene-bis-triazolium ligand precursor in an unusual rearrangement of norbornadiene to nortricyclyl.

Authors:  Jose A Mata; Eduardo Peris; Christopher Incarvito; Robert H Crabtree
Journal:  Chem Commun (Camb)       Date:  2003-01-21       Impact factor: 6.222

7.  Cyclopropenylidene carbene ligands in palladium C-C coupling catalysis.

Authors:  Duncan F Wass; Mairi F Haddow; Thomas W Hey; A Guy Orpen; Christopher A Russell; Richard L Wingad; Michael Green
Journal:  Chem Commun (Camb)       Date:  2007-04-17       Impact factor: 6.222

8.  N-heterocyclic carbenes: a new concept in organometallic catalysis.

Authors:  Wolfgang A Herrmann
Journal:  Angew Chem Int Ed Engl       Date:  2002-04-15       Impact factor: 15.336

9.  Facile splitting of hydrogen and ammonia by nucleophilic activation at a single carbon center.

Authors:  Guido D Frey; Vincent Lavallo; Bruno Donnadieu; Wolfgang W Schoeller; Guy Bertrand
Journal:  Science       Date:  2007-04-20       Impact factor: 47.728

10.  Allene formation by gold catalyzed cross-coupling of masked carbenes and vinylidenes.

Authors:  Vincent Lavallo; Guido D Frey; Shazia Kousar; Bruno Donnadieu; Guy Bertrand
Journal:  Proc Natl Acad Sci U S A       Date:  2007-08-13       Impact factor: 11.205
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  5 in total

1.  Theoretical study of the ring expansion reaction mechanism of cyclopropenylidene with azetidine.

Authors:  Xiaojun Tan; Weihua Wang; Qiao Sun; Ying Jing; Ping Li
Journal:  J Mol Model       Date:  2014-02-18       Impact factor: 1.810

2.  Phase-transfer and other types of catalysis with cyclopropenium ions.

Authors:  Jeffrey S Bandar; Anont Tanaset; Tristan H Lambert
Journal:  Chemistry       Date:  2015-03-27       Impact factor: 5.236

3.  A general strategy for regiocontrol in nickel-catalyzed reductive couplings of aldehydes and alkynes.

Authors:  Hasnain A Malik; Grant J Sormunen; John Montgomery
Journal:  J Am Chem Soc       Date:  2010-05-12       Impact factor: 15.419

Review 4.  Stable cyclic carbenes and related species beyond diaminocarbenes.

Authors:  Mohand Melaimi; Michèle Soleilhavoup; Guy Bertrand
Journal:  Angew Chem Int Ed Engl       Date:  2010-11-15       Impact factor: 15.336

5.  Reactivity of cyclic (alkyl)(amino)carbenes (CAACs) and bis(amino)cyclopropenylidenes (BACs) with heteroallenes: comparisons with their N-heterocyclic carbene (NHCs) counterparts.

Authors:  Glenn Kuchenbeiser; Michele Soleilhavoup; Bruno Donnadieu; Guy Bertrand
Journal:  Chem Asian J       Date:  2009-11-02
  5 in total

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