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Literature DB >> 15368380

Structural revision and total synthesis of azaspiracid-1, part 1: intelligence gathering and tentative proposal.

K C Nicolaou¹, Stepan Vyskocil, Theocharis V Koftis, Yoichi M A Yamada, Taotao Ling, David Y-K Chen, Wenjun Tang, Goran Petrovic, Michael O Frederick, Yiwei Li, Masayuki Satake.

Abstract

Entities: Chemical

Mesh：

Substances：

Year: 2004 PMID： 15368380 DOI： 10.1002/anie.200460695

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

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15 in total

1. Synthesis of the ABCD and ABCDE ring systems of azaspiracid-1.

Authors: Xiao-Ti Zhou; Rich G Carter
Journal: Chem Commun (Camb) Date: 2004-09-20 Impact factor: 6.222

Review 2. Constructing molecular complexity and diversity: total synthesis of natural products of biological and medicinal importance.

Authors: K C Nicolaou; Christopher R H Hale; Christian Nilewski; Heraklidia A Ioannidou
Journal: Chem Soc Rev Date: 2012-06-28 Impact factor: 54.564

3. Synthesis of the southern FGHI ring system of azaspiracid-1 and investigation into the controlling elements of C28- and C36-ketalization.

Authors: Xiao-Ti Zhou; Liang Lu; Daniel P Furkert; Charles E Wells; Rich G Carter
Journal: Angew Chem Int Ed Engl Date: 2006-11-20 Impact factor: 15.336

4. Synthesis of the C1-C26 northern portion of azaspiracid-1: kinetic versus thermodynamic control of the formation of the bis-spiroketal.

Authors: Xiao-Ti Zhou; Rich G Carter
Journal: Angew Chem Int Ed Engl Date: 2006-03-03 Impact factor: 15.336

Structural revision and total synthesis of azaspiracid-1, part 1: intelligence gathering and tentative proposal.

1. Synthesis of the ABCD and ABCDE ring systems of azaspiracid-1.

Review 2. Constructing molecular complexity and diversity: total synthesis of natural products of biological and medicinal importance.

3. Synthesis of the southern FGHI ring system of azaspiracid-1 and investigation into the controlling elements of C28- and C36-ketalization.

4. Synthesis of the C1-C26 northern portion of azaspiracid-1: kinetic versus thermodynamic control of the formation of the bis-spiroketal.

5. Total synthesis of atrochamins F, H, I, and J through cascade reactions.

6. Monoclonal antibodies with orthogonal azaspiracid epitopes.

7. Synthetic and Computational Studies on the ABC Trioxadispiroketal Subunit of the Marine Biotoxin Azaspiracid-1.

8. Microsphere-based immunoassay for the detection of azaspiracids.

9. Azaspiracid substituent at C1 is relevant to in vitro toxicity.

10. Involvement of caspase activation in azaspiracid-induced neurotoxicity in neocortical neurons.