Literature DB >> 1212225

The thermochemical characterization of sodium dithionite, flavin mononucleotide, flavin-adenine dinucleotide and methyl and benzyl viologens as low-potential reductants for biological systems.

G D Watts, A Burns.   

Abstract

The heat of reaction (deltaH) of Fe(CN)63-, Methyl Viologen, FMN and FAD with S2O42- in aqueous buffer solutions was measured calorimetrically. In addition deltaH values for reduction of Fe(CN)63-, FMN and FAD by reduced Methyl Viologen were determined. The resulting calorimetric data and corresponding E0 values were combined to yield thermodynamic data for these simple reducing agents in a form useful for applications to biological reactions. Thermodynamic data for the reduction of spinach ferredoxin are also presented.

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Year:  1975        PMID: 1212225      PMCID: PMC1172436          DOI: 10.1042/bj1520033

Source DB:  PubMed          Journal:  Biochem J        ISSN: 0264-6021            Impact factor:   3.857


  9 in total

1.  NITROGEN FIXATION: HYDROSULFITE AS ELECTRON DONOR WITH CELL-FREE PREPARATIONS OF AZOTOBACTER VINELANDII AND RHODOSPIRILLUM RUBRUM.

Authors:  W A BULEN; R C BURNS; J R LECOMTE
Journal:  Proc Natl Acad Sci U S A       Date:  1965-03       Impact factor: 11.205

2.  A new procedure for assay of bacterial hydrogenases.

Authors:  H D PECK; H GEST
Journal:  J Bacteriol       Date:  1956-01       Impact factor: 3.490

3.  Thermodynamic aspects of the potassium hexacyanoferrate(3)-(2) system. II. Reduction potential.

Authors:  G I Hanania; D H Irvine; W A Eaton; P George
Journal:  J Phys Chem       Date:  1967-06

4.  The enthalpy change accompanying the oxidation of ferrocytochrome c in the pH range 6-11 at 25 degrees.

Authors:  G D Watt; J M Sturtevant
Journal:  Biochemistry       Date:  1969-11       Impact factor: 3.162

Review 5.  Cytochrome c.

Authors:  E Margoliash; A Schejter
Journal:  Adv Protein Chem       Date:  1966

6.  The nitrogenase system from Azotobacter: two-enzyme requirement for N2 reduction, ATP-dependent H2 evolution, and ATP hydrolysis.

Authors:  W A Bulen; J R LeComte
Journal:  Proc Natl Acad Sci U S A       Date:  1966-09       Impact factor: 11.205

Review 7.  High-energy electrons in bacteria.

Authors:  J R Benemann; R C Valentine
Journal:  Adv Microb Physiol       Date:  1971       Impact factor: 3.517

8.  The enthalpy change for the reduction of nicotinamide--adenine dinucleotide.

Authors:  K Burton
Journal:  Biochem J       Date:  1974-11       Impact factor: 3.857

9.  Hydrogenase measurement with photochemically reduced methyl viologen.

Authors:  L Yu; M J Wolin
Journal:  J Bacteriol       Date:  1969-04       Impact factor: 3.490

  9 in total
  3 in total

1.  A VOLTAMMETRIC FLAVIN MICROELECTRODE FOR USE IN BIOFILMS.

Authors:  Hung Duc Nguyen; Ryan Renslow; Jerome Babauta; Bulbul Ahmed; Haluk Beyenal
Journal:  Sens Actuators B Chem       Date:  2012-01-03       Impact factor: 7.460

2.  Spectroscopic characterization and mechanistic investigation of P-methyl transfer by a radical SAM enzyme from the marine bacterium Shewanella denitrificans OS217.

Authors:  Kylie D Allen; Susan C Wang
Journal:  Biochim Biophys Acta       Date:  2014-09-16

Review 3.  Biohydrogen Production by the Thermophilic Bacterium Caldicellulosiruptor saccharolyticus: Current Status and Perspectives.

Authors:  Abraham A M Bielen; Marcel R A Verhaart; John van der Oost; Servé W M Kengen
Journal:  Life (Basel)       Date:  2013-01-17
  3 in total

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