Literature DB >> 11775674

Non-sequential processes for the transformation of a racemate into a single stereoisomeric product: proposal for stereochemical classification.

K Faber1.   

Abstract

Non-sequential processes which allow the transformation of a racemate into a single stereoisomeric product without the occurrence of an "undesired" isomer are classified according to their underlying stereochemistry. A re-definition of the term "de-racemization" is proposed.

Year:  2001        PMID： 11775674     DOI： 10.1002/1521-3765(20011203)7:23<5004::aid-chem5004>3.0.co;2-x

Source DB:  PubMed          Journal:  Chemistry        ISSN： 0947-6539            Impact factor:   5.236


  12 in total

1.  Mechanistic studies of the molybdenum-catalyzed asymmetric alkylation reaction.

Authors:  David L Hughes; Guy C Lloyd-Jones; Shane W Krska; Laure Gouriou; Veronique D Bonnet; Kevin Jack; Yongkui Sun; David J Mathre; Robert A Reamer
Journal:  Proc Natl Acad Sci U S A       Date:  2004-03-31       Impact factor: 11.205

2.  Single-operation deracemization of 3H-indolines and tetrahydroquinolines enabled by phase separation.

Authors:  Aaron D Lackner; Andrew V Samant; F Dean Toste
Journal:  J Am Chem Soc       Date:  2013-09-11       Impact factor: 15.419

3.  "It's a (Kinetic) Trap!" - Selectively Differentiating Allylic Azide Isomers.

Authors:  Joseph J Topczewski; Matthew R Porter
Journal:  Synlett       Date:  2018-07       Impact factor: 2.454

4.  Chemoenzymatic Dynamic Kinetic Asymmetric Transformations of β-Hydroxyketones.

Authors:  Simon Hilker; Daniels Posevins; C Rikard Unelius; Jan-E Bäckvall
Journal:  Chemistry       Date:  2021-10-05       Impact factor: 5.020

5.  Purification and characterization of an inverting stereo- and enantioselective sec-alkylsulfatase from the gram-positive bacterium Rhodococcus ruber DSM 44541.

Authors:  Mateja Pogorevc; Kurt Faber
Journal:  Appl Environ Microbiol       Date:  2003-05       Impact factor: 4.792

Review 6.  Asymmetric Catalysis Mediated by Synthetic Peptides, Version 2.0: Expansion of Scope and Mechanisms.

Authors:  Anthony J Metrano; Alex J Chinn; Christopher R Shugrue; Elizabeth A Stone; Byoungmoo Kim; Scott J Miller
Journal:  Chem Rev       Date:  2020-09-24       Impact factor: 60.622

7.  One-pot synthesis of enantiopure syn-1,3-diacetates from racemic syn/anti mixtures of 1,3-diols by dynamic kinetic asymmetric transformation.

Authors:  Michaela Edin; Johannes Steinreiber; Jan-E Bäckvall
Journal:  Proc Natl Acad Sci U S A       Date:  2004-04-06       Impact factor: 11.205

8.  Enantioselective synthesis of 3-arylquinazolin-4(3H)-ones via peptide-catalyzed atroposelective bromination.

Authors:  Matthew E Diener; Anthony J Metrano; Shuhei Kusano; Scott J Miller
Journal:  J Am Chem Soc       Date:  2015-09-18       Impact factor: 15.419

9.  Stereochemistry and Mechanism of Enzymatic and Non-Enzymatic Hydrolysis of Benzylic sec-Sulfate Esters.

Authors:  Michael Toesch; Markus Schober; Rolf Breinbauer; Kurt Faber
Journal:  European J Org Chem       Date:  2014-06-01

10.  Copper-catalysed asymmetric allylic alkylation of alkylzirconocenes to racemic 3,6-dihydro-2H-pyrans.

Authors:  Emeline Rideau; Stephen P Fletcher
Journal:  Beilstein J Org Chem       Date:  2015-12-03       Impact factor: 2.883
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