New open frameworks based on metal pyridylphosphonates.

A family of new 1D, 2D, and 3D coordination networks based on metal-pyridylphosphonates have been synthesized under hydro(solvo)thermal conditions. Zn(3-pyridylphosphonate)(bromide), 1, adopts a 1D ladder structure, while Co(4-pyridylphosphonate)(H(2)O)(3), 2, adopts a 2D grid structure. [Cu(2)(4-pyridylphosphonate)(2)]-2H(2)O, 3, [Cd(3-pyridylphosphonate)(2)]-DMSO, 4, Cd(4-pyridylphosphonate)(2), 5, and Cd(ethyl 4-pyridylphosphonate)(2), 6, all adopt 3D framework structures. While 3 possesses open channels that are occupied by water molecules, 4 exhibits cavities that accommodate DMSO guest molecules. The present work demonstrates that interesting open frameworks can be readily synthesized on the basis of metal pyridylphosphonates. Crystal data for 1: monoclinic space group C2/c; a = 15.267(4), b = 11.903(2), c = 10.380(2) A; beta = 98.68(2) degrees; Z = 8. Crystal data for 2: monoclinic space group P2(1)/c; a = 9.634(12), b = 7.611(9), c = 11.901(1) A; beta = 97.830(2) degrees; Z = 4. Crystal data for 3: triclinic spacegroup P one macro; a = 7.464(8), b = 9.203(1), c = 11.602(2) A; alpha = 100.289(1) degrees; beta = 104.532(1) degrees, gamma = 94.569(1) degrees; Z = 2. Crystal data for 4: tetragonal space group I4(1)/a; a = 15.114(2), b = 15.114(2), c = 13.128(3) A; Z = 8. Crystal data for 5: monoclinic space group P2(1)/c; a = 8.344(2), b = 10.589(2), c = 14.384(3) A; beta = 91.77(3) degrees; Z = 4. Crystal data for 6: monoclinic space group P2(1)/n; a = 5.606(1), b = 11.198(1), c = 14.176(2) A; beta = 94.518(1) degrees; Z = 2.