Literature DB >> 11296522

ESA mission ROSETTA will probe for chirality of cometary amino acids.

W H Thiemann1, U Meierhenrich.   

Abstract

New crucial theoretical investigations on the origin of biomolecular chirality are reviewed briefly. With the goal to investigate these theories our team is going to perform the 'chirality-experiment' in the near future with cometary matter. In 2012 the robotical lander RoLand will detach from the orbiter of the ROSETTA spacecraft and set down on the surface of comet 46P/Wirtanen in order to separate and identify cometary organic compounds via GC-MS in situ. Chiral organics will be separated into their enantiomers by application of 3 capillary columns coated with different kinds of stationary phases. Non-volatile compounds like amino acids will be derivatized in especially developed gas phase alkylation steps avoiding reactions in the liquid phase. The results of these preliminary gas phase reactions are presented in this article.

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Year:  2001        PMID: 11296522     DOI: 10.1023/a:1006718920805

Source DB:  PubMed          Journal:  Orig Life Evol Biosph        ISSN: 0169-6149            Impact factor:   1.950


  22 in total

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Journal:  Orig Life Evol Biosph       Date:  1999-05       Impact factor: 1.950

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Authors:  W Thiemann
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Authors:  J Oro; S Nakaparksin; H Lichtenstein; E Gil-Av
Journal:  Nature       Date:  1971-03-12       Impact factor: 49.962

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Journal:  Orig Life       Date:  1980-09

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Authors:  T C Chiang
Journal:  J Chromatogr       Date:  1980-06-13

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Journal:  Nature       Date:  1984 Aug 16-22       Impact factor: 49.962

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Journal:  Experientia       Date:  1992-10-15
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  6 in total

1.  A detailed study of the amino acids produced from the vacuum UV irradiation of interstellar ice analogs.

Authors:  Michel Nuevo; Geneviève Auger; Didier Blanot; Louis d'Hendecourt
Journal:  Orig Life Evol Biosph       Date:  2008-01-04       Impact factor: 1.950

2.  Anisotropy-Guided Enantiomeric Enhancement in Alanine Using Far-UV Circularly Polarized Light.

Authors:  Cornelia Meinert; Patrick Cassam-Chenaï; Nykola C Jones; Laurent Nahon; Søren V Hoffmann; Uwe J Meierhenrich
Journal:  Orig Life Evol Biosph       Date:  2015-03-14       Impact factor: 1.950

3.  Absolute optical chiral analysis using cavity-enhanced polarimetry.

Authors:  Lykourgos Bougas; Joseph Byron; Dmitry Budker; Jonathan Williams
Journal:  Sci Adv       Date:  2022-06-03       Impact factor: 14.957

4.  Photochemical concepts on the origin of biomolecular asymmetry.

Authors:  Uwe J Meierhenrich; Wolfram H P Thiemann
Journal:  Orig Life Evol Biosph       Date:  2004-02       Impact factor: 1.950

5.  Identification of diamino acids in the Murchison meteorite.

Authors:  Uwe J Meierhenrich; Guillermo M Muñoz Caro; Jan Hendrik Bredehöft; Elmar K Jessberger; Wolfram H-P Thiemann
Journal:  Proc Natl Acad Sci U S A       Date:  2004-06-11       Impact factor: 11.205

6.  Supernovae, neutrinos and the chirality of amino acids.

Authors:  Richard N Boyd; Toshitaka Kajino; Takashi Onaka
Journal:  Int J Mol Sci       Date:  2011-05-31       Impact factor: 5.923

  6 in total

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