| Literature DB >> 10836069 |
Abstract
[formula: see text] Platinum and palladium chiral bisphosphine complexes and their counterion effects in asymmetric Diels-Alder reactions have been investigated. The reaction of cyclopentadiene and various bidentate dienophiles in the presence of a catalytic amount of Pt(II)- or Pd(II)-BINAP complex proceeds with excellent endo/exo selectivity as well as endo enantioselectivity (up to 99% ee).Entities:
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Year: 1999 PMID： 10836069 DOI： 10.1021/ol990346i
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005