Literature DB >> 7338595

The stability of sarin and soman in dilute aqueous solutions and the catalytic effect of acetate ion.

R I Ellin, W A Groff, A Kaminskis.   

Abstract

The hydrolysis of aqueous solutions of organophosphonate compounds such as sarin and soman is a critical factor in biochemical and therapeutic studies. The ability to dilute and transport these compounds with assurance of their purity is imperative to the integrity of such studies. An enzymic method has been used to measure low levels of organophosphonates. Maximum stability data were determined in aqueous and isotonic saline solutions. Acetate ion was found to significantly accelerate hydrolysis.1

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Year:  1981        PMID: 7338595     DOI: 10.1080/03601238109372290

Source DB:  PubMed          Journal:  J Environ Sci Health B        ISSN: 0360-1234            Impact factor:   1.990


  5 in total

1.  Detection of aqueous phase chemical warfare agent degradation products by negative mode ion mobility time-of-flight mass spectrometry [IM(tof)MS].

Authors:  Wes E Steiner; Charles S Harden; Feng Hong; Steve J Klopsch; Herbert H Hill; Vincent M McHugh
Journal:  J Am Soc Mass Spectrom       Date:  2006-01-18       Impact factor: 3.109

2.  Half-life of chlorpyrifos oxon and other organophosphorus esters in aqueous solution.

Authors:  Oksana Lockridge; Laurent Verdier; Lawrence M Schopfer
Journal:  Chem Biol Interact       Date:  2019-08-08       Impact factor: 5.192

3.  The stability of soman and its stereoisomers in aqueous solution: toxicological considerations.

Authors:  C A Broomfield; D E Lenz; B MacIver
Journal:  Arch Toxicol       Date:  1986-12       Impact factor: 5.153

4.  Stability of aqueous solutions of sarin and soman: influence of concentration and an equation for determining concentration.

Authors:  M L Shih; R I Ellin
Journal:  Bull Environ Contam Toxicol       Date:  1984-07       Impact factor: 2.151

5.  Safe disposal of diisopropyl fluorophosphate (DFP).

Authors:  G Lunn; E B Sansone
Journal:  Appl Biochem Biotechnol       Date:  1994-11       Impact factor: 2.926

  5 in total

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