Literature DB >> 4525451

On the existence of a mono-vinyl d-urobilin.

M Chedekel, F A Bovey, A I Brewster, Z J Petryka, M Weimer, C J Watson, A Moscowitz, D A Lightner.   

Abstract

Chromic acid degradation of a d-urobilin, obtained after incubation of bilirubin in fecal bacterial cultures, gave methylvinylmaleimide and methylethylmaleimide. The d-urobilin, molecular weight 588, C(33)H(40)-N(4)O(6), clearly showed the presence of both vinyl and ethyl resonances in the nuclear magnetic resonance spectrum. These results point unambiguously to a urobilin structure with one vinyl and one ethyl beta-substituent.

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Year:  1974        PMID: 4525451      PMCID: PMC388283          DOI: 10.1073/pnas.71.5.1599

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  9 in total

1.  Composition of the urobilin group in urine bile, and feces and the significance of variations in health and disease.

Authors:  C J WATSON; M WEIMER
Journal:  J Lab Clin Med       Date:  1959-07

2.  The isolation of crystalline d-urobilinogen.

Authors:  P T LOWRY; R CARDINAL; S COLLINS; C J WATSON
Journal:  J Biol Chem       Date:  1956-02       Impact factor: 5.157

3.  A further study of crystalline d-urobilin.

Authors:  C J WATSON; P T LOWRY
Journal:  J Biol Chem       Date:  1956-02       Impact factor: 5.157

4.  The effect of aureomycin on urobilinogen formation and the fecal flora.

Authors:  V M SBOROV; A R JAY; C J WATSON
Journal:  J Lab Clin Med       Date:  1951-01

5.  Structure of d-urobilin.

Authors:  S D Killilea; P O'Carra
Journal:  Biochem J       Date:  1972-10       Impact factor: 3.857

6.  Gold from dross: the first century of the urobilinoids.

Authors:  C J Watson
Journal:  Ann Intern Med       Date:  1969-04       Impact factor: 25.391

7.  [Degradation of bile pigments with chromic acid and chromate].

Authors:  W Rüdiger
Journal:  Hoppe Seylers Z Physiol Chem       Date:  1969-11

8.  Mass spectrometry and ferric chloride oxidation applied to urobilinoid structures.

Authors:  D A Lightner; A Moscowitz; Z J Petryka; S Jones; M Weimer; E Davis; N A Beach; C J Watson
Journal:  Arch Biochem Biophys       Date:  1969-05       Impact factor: 4.013

9.  Bilirubin and urobilins in germfree, ex-germfree, and conventional rats.

Authors:  B E GUSTAFSSON; L S LANKE
Journal:  J Exp Med       Date:  1960-12-01       Impact factor: 14.307

  9 in total
  1 in total

1.  Studies of the conformation of bilirubin and its dimethyl ester in dimethyl sulphoxide solutions by nuclear magnetic resonance.

Authors:  D Kaplan; G Navon
Journal:  Biochem J       Date:  1982-03-01       Impact factor: 3.857

  1 in total

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