| Literature DB >> 35632002 |
Jonghun Lim1,2, Hyungtae Cho1, Kwon-Chan Son3, Yup Yoo1,2, Junghwan Kim1.
Abstract
In this work, alternative evaporation processes for PLA production were designed with economic assessment. The suggested processes are the multiple-effect evaporation (MEE) process and thermal vapor recompression (TVR)-assisted evaporation process. First, the MEE process can efficiently reuse waste heat by additional column installation, thereby reducing the steam energy consumption. The proposed MEE process involves five columns, and after the evaporation in each column, the waste heat of the emitted vapor is reused to heat steam in the reboiler of the next column. Second, the suggested TVR-assisted evaporation process utilizes an additional steam ejector and recovers waste heat from the emitted vapor by increasing the pressure using high-pressure driving steam at the steam ejector. Each alternative process was modeled to predict the steam energy consumption, and to determine the cost-optimal process; the total annualized cost (TAC) of each alternative process was calculated as evaluation criteria. In the simulation results, the alternative processes using MEE and TVR reduced the steam consumption by 71.36% and 89.97%, respectively, compared to the conventional process. As a result of economic assessment, the cost-optimal process is the alternative process using TVR and the TAC can be decreased by approximately 90%.Entities:
Keywords: multiple-effect evaporation; poly-lactic acid; thermal vapor recompression
Year: 2022 PMID: 35632002 PMCID: PMC9143702 DOI: 10.3390/polym14102120
Source DB: PubMed Journal: Polymers (Basel) ISSN: 2073-4360 Impact factor: 4.967
Figure 1Simplified diagram of conventional evaporation process model using SEE.
Specifications of conventional process model.
| Block | Description | Specification | Value | Unit |
|---|---|---|---|---|
| DC | Distillation column | Distillate rate | 147,565 | kg/h |
| Number of stages | 11 | |||
| Stage 1/Condenser pressure | 3 | kg/cm2·g | ||
| Stage pressure drop | 0.01 | kg/cm2·g | ||
| Reboiler outlet molar vapor fraction | 0.2 | |||
| FD | Flash drum | Pressure | 3 | kg/cm2·g |
| HX-F1 | Heat exchanger | Exchanger duty | 10 | MMKcal/h |
| Minimum temperature approach | 5 | °C | ||
| HX-F2 | Heat exchanger | Hot/cold outlet temperature approach | 5 | K |
| Minimum temperature approach | 5 | °C | ||
| P1 | Centrifugal pump | Discharge pressure | 8 | kg/cm2·g |
| P2 | Centrifugal pump | Discharge pressure | 8 | kg/cm2·g |
| REB | Heat exchanger | Hot stream outlet vapor fraction | 0.01 | |
| Minimum temperature approach | 5 | °C |
Figure 2Simplified diagram of alternative evaporation process model using MEE.
Specification of alternative process model using MEE.
| Block | Description | Specification | Value | Unit |
|---|---|---|---|---|
| EVA1 | Distillation column | Distillate rate | 24,300 | kg/h |
| Number of stages | 11 | |||
| Stage 1/condenser pressure | 7.5 | kg/cm2·g | ||
| Stage pressure drop | 0.01 | kg/cm2·g | ||
| Reboiler outlet molar vapor fraction | 0.2 | |||
| EVA2 | Distillation column | Distillate rate | 26,800 | kg/h |
| Number of stages | 11 | |||
| Stage 1/condenser pressure | 6.1 | kg/cm2·g | ||
| Stage pressure drop | 0.01 | kg/cm2·g | ||
| Reboiler outlet molar vapor fraction | 0.2 | |||
| EVA3 | Distillation column | Distillate rate | 28,800 | kg/h |
| Number of stages | 11 | |||
| Stage 1/condenser pressure | 4.71 | kg/cm2·g | ||
| Stage pressure drop | 0.01 | kg/cm2·g | ||
| Reboiler outlet molar vapor fraction | 0.2 | |||
| EVA4 | Distillation column | Distillate rate | 32,300 | kg/h |
| Number of stages | 11 | |||
| Stage 1/condenser pressure | 3.25 | kg/cm2·g | ||
| Stage pressure drop | 0.01 | kg/cm2·g | ||
| Reboiler outlet molar vapor fraction | 0.2 | |||
| EVA5 | Distillation column | Distillate rate | 15,000 | kg/h |
| Number of stages | 11 | |||
| Stage 1/condenser pressure | 1.1 | kg/cm2·g | ||
| Stage pressure drop | 0.01 | kg/cm2·g | ||
| Reboiler outlet molar vapor fraction | 0.2 | |||
| F1 | Flash drum | Pressure | 7.5 | kg/cm2·g |
| F2 | Flash drum | Pressure | 6.1 | kg/cm2·g |
| F3 | Flash drum | Pressure | 4.71 | kg/cm2·g |
| F4 | Flash drum | Pressure | 3.25 | kg/cm2·g |
| F5 | Flash drum | Pressure | 1.1 | kg/cm2·g |
| HX-1–5 | Heat exchanger | Cold stream outlet vapor fraction | 0.2 | |
| HX-FEED | Heat exchanger | Exchanger duty | 10 | MMKcal/h |
| Minimum temperature approach | 5 | °C | ||
| HX-STM5, HX-WW | Heat exchanger | Hot/cold outlet temperature approach | 5 | K |
| Minimum temperature approach | 5 | °C | ||
| P1 and P2 | Centrifugal pump | Discharge pressure | 8 | kg/cm2·g |
Figure 3Simplified diagram of alternative process model using TVR.
Specifications of alternative process model using TVR.
| Block | Description | Specification | Value | Unit |
|---|---|---|---|---|
| DC | Distillation column | Distillate rate | 141,260 | kg/h |
| Number of stages | 11 | |||
| Stage 1/condenser pressure | −0.35 | kg/cm2·g | ||
| Stage pressure drop | 0.01 | kg/cm2·g | ||
| Reboiler outlet molar vapor fraction | 0.2 | |||
| HX-F1 | Heat exchanger | Hot/cold outlet temperature approach | 5 | K |
| Minimum temperature approach | 5 | K | ||
| P1 | Centrifugal pump | Discharge pressure | 1 | kg/cm2·g |
| REB | Heat exchanger | Hot stream outlet vapor fraction | 0.01 | |
| Minimum temperature approach | 5 | K | ||
| EJECTOR | Steam ejector | Pressure | 1.2 | kg/cm2·g |
Simulation results for conventional process.
| Classification | FEED | PRODUCT | VAPOR | MP-IN | Units |
|---|---|---|---|---|---|
| Temperature | 25 | 159.19 | 143.3 | 179.27 | °C |
| Pressure | 0 | 3.1 | 3 | 9 | kg/cm2·g |
| Mass flow of water | 145,440 | 5384 | 147,565 | 161,726 | kg/h |
| Mass flow of LA | 16,160 | 16,151 | - | - | kg/h |
| Total mass flow | 161,600 | 21,535 | 147,565 | 161,726 | kg/h |
Simulation results for alternative evaporation process using MEE.
| Classification | FEED | PRODUCT | VAPOR5 | MP-IN | Units |
|---|---|---|---|---|---|
| Temperature | 25 | 137.25 | 121.83 | 179.27 | °C |
| Pressure | 0 | 1.2 | 1.1 | 9 | kg/cm2·g |
| Mass flow of water | 145,440 | 5339 | 35,393 | 45,800 | kg/h |
| Mass flow of LA | 16,160 | 16,017 | - | - | kg/h |
| Mass flows | 161,600 | 21,356 | 35,393 | 45,800 | kg/h |
Simulation results for the alternative evaporation process using TVR.
| Classification | FEED | PRODUCT | VAPOR | MP-IN | Units |
|---|---|---|---|---|---|
| Temperature | 25 | 104.91 | 88.82 | 179.27 | °C |
| Pressure | 0 | −0.25 | −0.35 | 9 | kg/cm2·g |
| Mass flow of water | 145,440 | 5387 | 147,554 | 16,100 | kg/h |
| Mass flow of LA | 16,160 | 16,160 | − | − | kg/h |
| Mass flows | 161,600 | 21,546 | 147,554 | 16,100 | kg/h |
EAC of each process.
| Classification | Conventional Process Using SEE | Alternative Process Using MEE | Alternative Process Using TVR |
|---|---|---|---|
|
| |||
| Purchased equipment | 2,064,500 | 6,897,400 | 2,383,723 |
| Instruments | 970,315 | 3,241,778 | 1,120,350 |
| Installation | 371,610 | 1,241,532 | 429,070 |
| Piping | 1,362,570 | 4,552,284 | 1,573,257 |
| Electrical | 227,095 | 758,714 | 262,209 |
|
| |||
| Buildings | 371,610 | 1,241,532 | 429,070 |
| Yard Improvements | 206,450 | 689,740 | 238,372 |
| Service facilities | 1,445,150 | 4,828,180 | 1,668,606 |
| Land | 123,870 | 413,844 | 143,023 |
|
| |||
| Engineering | 681,285 | 2,276,142 | 786,628 |
| Construction | 846,445 | 2,827,934 | 977,326 |
| Contractor’s fee | 141,418 | 472,471 | 163,285 |
| Contigency | 282,836 | 944,943 | 326,570 |
|
| 1,364,273 | 4,557,974 | 1,575,224 |
|
| 9,095,154 | 30,386,495 | 10,501,494 |
|
| 10,459,427 | 34,944,470 | 12,076,718 |
|
| 1,217,514 | 3,798,312 | 1,465,557 |
AOC of each process.
| Classification | Conventional Process Using SEE | Alternative Process Using MEE | Alternative Process Using TVR | Unit |
|---|---|---|---|---|
| Electricity consumption | 146 | 153 | 60 | kW |
| Steam consumption | 162 | 46 | 16 | ton/h |
| Electricity cost | 82,888 | 87,135 | 34,039 | $/year |
| Steam cost | 51,511,930 | 14,752,276 | 5,165,335 | $/year |
|
| 51,594,818 | 14,839,411 | 5,199,374 | $/year |
Figure 4Calculated TCI, EAC, AOC, and TAC of each process.