Literature DB >> 35145733

A cuboidal [Cu4(SO4)4] structure supported by β-picoline ligands.

Ava M Park1, James A Golen2, David R Manke2.   

Abstract

The solid-state structure of the cobalt-β-picoline-sulfate complex tetra-μ3-sulfato-tetra-kis-[bis-(3-methyl-pyridine)-cobalt(II)], [Co4(SO4)4(C6H7N)8], is reported. The tetra-meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry. © Park et al. 2022.

Entities:  

Keywords:  cobalt complexes; coordination chemistry; crystal structure; picoline; sulfate; transition metal

Year:  2022        PMID： 35145733      PMCID： PMC8819428          DOI： 10.1107/S2056989022000780

Source DB:  PubMed          Journal:  Acta Crystallogr E Crystallogr Commun


  8 in total

1.  More crystal field theory in action: the metal-4-picoline (pic)-sulfate [M(pic)x]SO4 complexes (M = Fe, Co, Ni, Cu, Zn, and Cd).

Authors:  Duyen N K Pham; Mrittika Roy; Ava Kreider-Mueller; James A Golen; David R Manke
Journal:  Acta Crystallogr C Struct Chem       Date:  2019-04-15       Impact factor: 1.172

2.  First-row transition metal-pyridine (py)-sulfate [(py)xM](SO4) complexes (M = Ni, Cu and Zn): crystal field theory in action.

Authors:  Mrittika Roy; Duyen N K Pham; Ava Kreider-Mueller; James A Golen; David R Manke
Journal:  Acta Crystallogr C Struct Chem       Date:  2018-02-05       Impact factor: 1.172

3.  iotbx.cif: a comprehensive CIF toolbox.

Authors:  Richard J Gildea; Luc J Bourhis; Oleg V Dolomanov; Ralf W Grosse-Kunstleve; Horst Puschmann; Paul D Adams; Judith A K Howard
Journal:  J Appl Crystallogr       Date:  2011-10-29       Impact factor: 3.304

4.  SHELXT - integrated space-group and crystal-structure determination.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A Found Adv       Date:  2015-01-01       Impact factor: 2.290

5.  Crystal structure refinement with SHELXL.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr C Struct Chem       Date:  2015-01-01       Impact factor: 1.172

6.  The crystal structures of iron and cobalt pyridine (py)-sulfates, [Fe(SO4)(py)4] n and [Co3(SO4)3(py)11] n.

Authors:  Duyen N K Pham; Mrittika Roy; Ava Kreider-Mueller; James A Golen; David R Manke
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2018-05-31

7.  The varied structures of cobalt(II)-pyridine (py)-sulfate: [Co(SO4)(py)4] n , [Co2(SO4)2(py)6] n , and [Co3(SO4)3(py)11] n.

Authors:  Ava M Park; Duyen N K Pham; James A Golen; David R Manke
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2019-11-19

8.  Use of intensity quotients and differences in absolute structure refinement.

Authors:  Simon Parsons; Howard D Flack; Trixie Wagner
Journal:  Acta Crystallogr B Struct Sci Cryst Eng Mater       Date:  2013-05-17
  8 in total
  1 in total

1.  Erratum: A cuboidal [Co4(SO4)4] structure supported by β-picoline ligands. Corrigendum.

Authors:  Ava M Park; James A Golen; David R Manke
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2022-03-01
  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.