Literature DB >> 35079415

Crystal structure and Hirshfeld surface analysis of 2,2,2-tri-fluoro-1-(7-methyl-imidazo[1,2-a]pyridin-3-yl)ethan-1-one.

Firudin I Guseinov1,2, Konstantin I Kobrakov1, Bogdan I Ugrak2, Zeliha Atioğlu3, Mehmet Akkurt4, Ajaya Bhattarai5.   

Abstract

The bicyclic imidazo[1,2-a]pyridine core in the mol-ecule of the title compound, C10H7F3N2O, is planar within 0.004 (1) Å. In the crystal, the mol-ecules are linked by pairs of C-H⋯N and C-H⋯O hydrogen bonds, forming strips. These strips are connected by the F⋯F contacts into layers, which are further joined by π-π stacking inter-actions. The Hirshfeld surface analysis and fingerprint plots reveal that mol-ecular packing is governed by F⋯H/H⋯F (31.6%), H⋯H (16.8%), C⋯H/H⋯C (13.8%) and O⋯H/H⋯O (8.5%) contacts. © Guseinov et al. 2022.

Entities:  

Keywords:  F⋯F contacts; Hirshfeld surface analysis; crystal structure; hydrogen bonds; imidazo[1,2-a]pyridine

Year:  2022        PMID: 35079415      PMCID: PMC8739203          DOI: 10.1107/S2056989021012676

Source DB:  PubMed          Journal:  Acta Crystallogr E Crystallogr Commun


  8 in total

1.  2-(Ethyl-sulfin-yl)imidazo[1,2-a]pyridine-3-sulfonamide.

Authors:  Yaling Gong; Haixia Ma; Jing Li
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2012-04-13

Review 2.  Synthesis of imidazo[1,2-a]pyridines: a decade update.

Authors:  Avik Kumar Bagdi; Sougata Santra; Kamarul Monir; Alakananda Hajra
Journal:  Chem Commun (Camb)       Date:  2015-01-31       Impact factor: 6.222

3.  Resonance Assisted Chalcogen Bonding as a New Synthon in the Design of Dyes.

Authors:  Atash V Gurbanov; Maxim L Kuznetsov; Kamran T Mahmudov; Armando J L Pombeiro; Giuseppe Resnati
Journal:  Chemistry       Date:  2020-10-13       Impact factor: 5.236

4.  Hydrogen bond assisted activation of a dinitrile towards nucleophilic attack.

Authors:  Maximilian N Kopylovich; Kamran T Mahmudov; Archana Mizar; Armando J L Pombeiro
Journal:  Chem Commun (Camb)       Date:  2011-05-23       Impact factor: 6.222

5.  Noncovalent Interactions at Lanthanide Complexes.

Authors:  Kamran T Mahmudov; Fatali E Huseynov; Vusala A Aliyeva; M Fátima C Guedes da Silva; Armando J L Pombeiro
Journal:  Chemistry       Date:  2021-08-06       Impact factor: 5.236

6.  2-Methyl-6-(trifluoro-meth-yl)imidazo[1,2-a]pyridine-3-carbonitrile.

Authors:  Hoong-Kun Fun; Mohd Mustaqim Rosli; D J Madhu Kumar; D Jagadeesh Prasad; G K Nagaraja
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2011-02-05

7.  SHELXT - integrated space-group and crystal-structure determination.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr A Found Adv       Date:  2015-01-01       Impact factor: 2.290

8.  Crystal structure refinement with SHELXL.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr C Struct Chem       Date:  2015-01-01       Impact factor: 1.172

  8 in total

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