| Literature DB >> 34322666 |
R Williams1, R Duvall1, V Kilaru1, G Hagler1, L Hassinger2, K Benedict3, J Rice3, A Kaufman3, R Judge4, G Pierce5, G Allen6, M Bergin7, R C Cohen8, P Fransioli9, M Gerboles10, R Habre11, M Hannigan12, D Jack13, P Louie14, N A Martin15, M Penza16,17, A Polidori18, R Subramanian19, K Ray20, J Schauer21, E Seto22, G Thurston23, J Turner24, A S Wexler25, Z Ning26.
Abstract
The United States Environmental Protection Agency held an international two-day workshop in June 2018 to deliberate possible performance targets for non-regulatory fine particulate matter (PM2.5) and ozone (O3) air sensors. The need for a workshop arose from the lack of any market-wide manufacturer requirement for Ozone documented sensor performance evaluations, the lack of any independent third party or government-based sensor performance certification program, and uncertainty among all users as to the general usability of air sensor data. A multi-sector subject matter expert panel was assembled to facilitate an open discussion on these issues with multiple stakeholders. This summary provides an overview of the workshop purpose, key findings from the deliberations, and considerations for future actions specific to sensors. Important findings concerning PM2.5 and O3 sensors included the lack of consistent performance indicators and statistical metrics as well as highly variable data quality requirements depending on the intended use. While the workshop did not attempt to yield consensus on any topic, a key message was that a number of possible future actions would be beneficial to all stakeholders regarding sensor technologies. These included documentation of best practices, sharing quality assurance results along with sensor data, and the development of a common performance target lexicon, performance targets, and test protocols.Entities:
Keywords: Low-cost air quality sensors; PM2.5; Performance targets
Year: 2019 PMID: 34322666 PMCID: PMC8314253 DOI: 10.1016/j.aeaoa.2019.100031
Source DB: PubMed Journal: Atmos Environ X ISSN: 2590-1621
Frequency and number of times information sources contained DQOs/MQOs[a] for different performance attributes (Williams et al., 2018).
| Performance Characteristic/DQI[ | PM2.5 | PM10 | Carbon Monoxide (CO) | Nitrogen Dioxide (NO2) | Sulfur Dioxide (SO2) | Ozone (O3) |
|---|---|---|---|---|---|---|
| Accuracy/Uncertainty | 84% (16) | 77% (10) | 65% (11) | 68% (15) | 80% (4) | 76% (19) |
| Bias | 5% (1) | 8% (1) | 18% (3) | 9% (2) | 40% (2) | 16% (4) |
| Completeness | 26% (5) | 31% (4) | 12% (2) | 14% (3) | 40% (2) | 16% (4) |
| Detection Limit | 26% (5) | 8% (1) | 47% (8) | 32% (7) | 80% (4) | 24% (6) |
| Measurement Duration | 26% (5) | 8% (1) | 18% (3) | 14% (3) | 0% (0) | 20% (5) |
| Measurement Frequency | 26% (5) | 15% (2) | 35% (6) | 23% (5) | 0% (0) | 32% (8) |
| Measurement Range | 47% (9) | 46% (6) | 35% (6) | 32% (7) | 80% (4) | 40% (10) |
| Precision | 42% (8) | 31% (4) | 29% (5) | 36% (8) | 80% (4) | 32% (8) |
| Response Time | 0% (0) | 0% (0) | 29% (5) | 32% (7) | 80% (4) | 20% (5) |
| Selectivity | 11% (2) | 8% (1) | 24% (4) | 23% (5) | 80% (4) | 16% (4) |
| Other[ | 5% (1) | 8% (1) | 0% (0) | 0% (0) | 0% (0) | 8% (2) |
| All Information Sources | 40% (19) | 27% (13) | 35% (17) | 46% (22) | 10% (5) | 52% (25) |
MQO =Measurement Quality Objective.
Totals across all performance characteristics for a given pollutant are always greater than the figures shown in the last row because a single information source may contain performance requirements for more than one pollutant and/or performance characteristic.
“Other” category captures all performance characteristics not among the 10 listed.
Measurement parameters for air sensor performance (Penza, 2018).
| Transducer | Sensitivity | Selectivity | Stability | Limit of Detection | Open Questions |
|---|---|---|---|---|---|
| Electrochemical | High | Variable | Improved | ppb | Interference, calibration, signal processing |
| Spectroscopic and NDIR | High | Variable | Low | ppm | Interference, calibration, signal processing |
| Photo-Ionization Detector | High | Low | Improved | ppb | Interference, calibration, signal processing |
| Optical Particulate Counter | High | Improved | Improved | μg/m3 | Interference, calibration, signal processing |
| Metal Oxides | High | Variable | Low | ppb | Interference, calibration, signal processing |
| Pellistors | High | Low | Improved | ppm | Interference, calibration, signal processing |
PM2.5 criteria/DQIs defined relative to any instrumentation for regulatory air monitoring requirements in the U.S., EU, and China (Williams et al., 2018; Table B1). Note: A description of the terms and abbreviations are listed in Table S3.
| Performance Attributes/DQIs | Decision Support |
|---|---|
| Accuracy/Uncertainty | RPDflow:
|
| Bias | None |
| Completeness | Completeness (%): 85, ≥90 |
| Detection Limit | Detection limit (μg/m3):
|
| Measurement Duration | Measurement duration: 60min |
| Measurement Frequency | Flow rate measurement intervals: ≤30s |
| Measurement Range | Concentration range: 0–1000
μg/m3, ( |
| Precision | CVconc: ≤5%, ≤
15% |
| Response Time | None |
| Selectivity | Temperature influence: zero temperature
dependence under |
Fig. 1.Sensor performance relating to changes in temperature, RH, and drift. Example of a low-cost NO2 electrochemical sensor with an O3 filter. Test is displaying responses to changes in temperature, relative humidity, and drift over time (Ning, 2018).
Fig. 2.Plots demonstrating the 1 and 60-min averaging times of 35 collocated low-cost (∼$100 USD) Sharp GP2Y10 light scattering sensors during a 48-h deployment (Hannigan, 2018).
Desirable performance features of wearable PM sensors established as part of the Los Angeles PRISMS Center BREATHE informatics platform and pediatric asthma panel study (Habre, 2018).
| Parameter | Selection Criteria |
|---|---|
| Accuracy and precision | As close as possible to equivalent FRM/FEM±15% or less |
| Interferences | Minimal |
| Data collection, storage, and retrieval | Internal storage, wireless, secure and real-time communication |
| Energy consumption | Minimal: Battery life ~8–12 h and/or simple charging requirements |
| Participant burden | Low: Low weight, low noise, unobtrusive form factor, “wearable”, flexible wear options |
| Durability, known performance | Consistent and proven performance, across microenvironments and mobility levels, low drift over time |
Suggested precision and accuracy targets for low-cost sensors to benefit a wide range of application scenarios (Schauer, 2018).
| Application | Precision | Accuracy |
|---|---|---|
| Comparison to Standards | ± 10% | ± 10% |
| Scaling Filter Based Measurements | ± 50% | ± 50% |
| Spatial Gradients | ± 10% | ± 25% |
| Microenvironmental Monitoring | ± 25% | ± 25% |
| Meteorological Drives | ± 10% | ± 25% |
| Source Tracking | ± 50% | ± 50% |
| Intervention and Control Measures | ± 25% | ± 25% |
Summary of PM2.5 sensor performance attributes from the subject matter expert discussion on Day 3.
| Technology Attribute | Minimum Acceptable Value/Range
(count)[ | Estimated Minimum Acceptable Value/Range |
|---|---|---|
| Accuracy | 10% (2) | Range: 10%–100% |
| 15% (2) | Median: 25% | |
| Bias | 2.5% (1) | Range: 1 μg/m3 – 5 μg/m3 |
| 10% (2) | or 2.5%–50% | |
| 20% (1) | Median: 2 μg/m3 or 15% | |
| Correlation | r = 0.84 (1) | Range: r = 0.84–0.95 |
| r = 0.87 (1) r = 0.89 (2) r = 0.95 (1) | Median: r = 0.89 | |
| Detection Limit | 1 μg/m3 (1) | Range: 2–4 μg/m3 |
| 2 μg/m3 (1) | Median: 2 μg/m3 | |
| Precision | 10% (1) | Range: 10%–50% |
| 20% (2) | Median: 23% | |
Numbers (X) represent the count of SEs who suggested each metric.
(Note: The listed sensor performance values should not be considered suggestive about any specific US EPA recommended means of establishing such a value).
Summary of O3 sensor performance attributes from the subject matter expert discussion on Day 3. (Note: The listed sensor performance values should not be considered suggestive about any specific US EPA recommended means of establishing such a value).
| Technology Attribute | Minimum Acceptable Value/Range
(count)[ | Estimated Minimum Acceptable Value/Range |
|---|---|---|
| Accuracy | 7% (1) | Range: 7%–20% |
| 10% (2) | Median: 13% | |
| Bias | 5% (1) | Range: 5%–25% |
| 10% (1) | or 2 ppb-5 ppb | |
| 25% (1) | Median: 12.5% or 4 ppb | |
| Correlation | r = 0.74 (1) | Range: r = 0.74–0.95 |
| r = 0.89 (1) r = 0.95 (1) | Median: r = 0.86 | |
| Detection Limit | 2 ppb (1) | Range: 2ppb-10 ppb |
| 10 ppb(1) | Median: 5 ppb | |
| Precision | 7% (1) | Range: 7%–20% or 5 ppb- |
| 15% (2) | Median: 15% or 102 ppb | |
| Range | 0–180 ppb (1) | Range: 0 ppb-200 ppb |
| 0–200 ppb (1) | Median: 100 ppb | |
Numbers (X) represent the count of SEs who suggested each metric.
Breakdown of an example tiering system for sensor performance targets (Allen, 2018).
| Tier | Performance targets |
|---|---|
| 0 – Just Don’t Use It | R2 < 0.25 or RMSD > 100% |
| 1 – Qualitative | R2 0.25 to 0.50, RMSD < 100% |
| 2 – Semi-Quantitative | R2 0.50 to 0.75, RMSD < 50%, bias < 50% |
| 3 – Reasonably Quantitative | R2 0.75 to 0.90, RMSD < 20%, bias < 30% |
| 4 – Almost Regulatory | R2 > 0.90, RMSD < 10%, bias < 15% |