Literature DB >> 34125543

Hydroperoxidations of Alkenes using Cobalt Picolinate Catalysts.

Zulema Peralta-Neel1, K A Woerpel1.   

Abstract

Hydroperoxides were synthesized in one step from various alkenes using Co(pic)2 as the catalyst with molecular oxygen and tetramethyldisiloxane (TMDSO). The hydration product could be obtained using a modified catalyst, Co(3-mepic)2, with molecular oxygen and phenylsilane. Formation of hydroperoxides occurred through a rapid Co-O bond metathesis of a peroxycobalt compound with isopropanol.

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Year:  2021        PMID： 34125543      PMCID： PMC9022486          DOI： 10.1021/acs.orglett.1c01489

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.072


  24 in total

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8.  Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.

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Review 9.  Antitumor activity of artemisinin and its derivatives: from a well-known antimalarial agent to a potential anticancer drug.

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