Literature DB >> 27461578

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins.

Steven W M Crossley1, Carla Obradors1, Ruben M Martinez1, Ryan A Shenvi1.   

Abstract

Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas reactions to form a wide range of Markovnikov-selective olefin radical hydrofunctionalizations. We cover the development of the field and review contributions to reaction invention, mechanism, and application to complex molecule synthesis. We also provide a mechanistic framework for understanding this compendium of radical reactions.

Entities:  

Year:  2016        PMID： 27461578      PMCID： PMC5872827          DOI： 10.1021/acs.chemrev.6b00334

Source DB:  PubMed          Journal:  Chem Rev        ISSN： 0009-2665            Impact factor:   60.622


  192 in total

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  103 in total

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