MXene (Ti3C2Tx) Functionalized Short Carbon Fibers as a Cross-Scale Mechanical Reinforcement for Epoxy Composites.

The surface modification technology of carbon fibers (CFs) have achieved considerable development, and it has achieved great success in improving the interfacial shear strength (IFSS) of the polymer matrix. Among them, MXene (Ti3C2Tx) functionalized CFs have been proven to improve the interface performance significantly. Unfortunately, the results on the microscopic scale are rarely applied to the preparation of macroscopic composite materials. Herein, the process of MXene functionalized CFs were attempted to be extended to short carbon fibers (SCFs) and used to strengthen epoxy materials. The results show that the cross-scale reinforcement of MXene functionalized SCFs can be firmly bonded to the epoxy matrix, which significantly improves the mechanical properties. Compared to neat epoxy, the tensile strength (141.2 ± 2.3 MPa), flexural strength (199.3 ± 8.9 MPa) and critical stress intensity factor (KIC, 2.34 ± 0.04 MPa·m1/2) are increased by 100%, 67%, and 216%, respectively.