Tricarbonylrhenium(I)(α-diimine) complexes are of importance because of their strong cytotoxic and fluorescence properties. Syntheses of such complexes were achieved through a two-step process. First, the pentylcarbonato complexes, fac-(CO)3(α-diimine)ReOC(O)OC5H11 were synthesized through a microwave-assisted reaction of Re2(CO)10, α-diimine, 1-pentanol and CO2 in a few hours. Second, the pentylcarbonato complexes are treated with carboxylic, sulfonic and halo acids to obtain the corresponding carboxylato, sulfonato and halido complexes. This is the first example of conversion of Re2(CO)10 into a rhenium carbonyl complex through microwave-assisted reaction.
Tricarbonylrhenium(I)(α-diimine) complexes are of importance because of their strong cytotoxic and fluorescence properties. Syntheses of such complexes were achieved through a two-step process. First, the n class="Chemical">pentylcarbonato complexes, fac-(CO)3(α-diimine)ReOC(O)OC5H11 were synthesized through a microwave-assisted reaction of Re2(CO)10, α-diimine, 1-pentanol and CO2 in a few hours. Second, the pentylcarbonato complexes are treated with carboxylic, sulfonic and halo acids to obtain the corresponding carboxylato, sulfonato and halido complexes. This is the first example of conversion of Re2(CO)10 into a rhenium carbonyl complex through microwave-assisted reaction.
Authors: Paul T Wilder; David J Weber; Angela Winstead; Sabreea Parnell; Tiara V Hinton; Monet Stevenson; Dipak Giri; Samira Azemati; Pola Olczak; Brent V Powell; Tijesunimi Odebode; Solomon Tadesse; Yongchao Zhang; Saroj K Pramanik; James M Wachira; Sujan Ghimire; Pumtiwitt McCarthy; Alexis Barfield; Hirendra N Banerjee; Chao Chen; James A Golen; Arnold L Rheingold; Jeanette A Krause; Douglas M Ho; Peter Y Zavalij; Roosevelt Shaw; Santosh K Mandal Journal: Mol Cell Biochem Date: 2017-09-14 Impact factor: 3.396
Authors: Andrew E C Green; Patrick W Causey; Anika S Louie; Andrea F Armstrong; Laura E Harrington; John F Valliant Journal: Inorg Chem Date: 2006-07-24 Impact factor: 5.165
Authors: Inmaculada Picón-Ferrer; Francisco Hueso-Ureña; Nuria A Illán-Cabeza; Sonia B Jiménez-Pulido; José M Martínez-Martos; María J Ramírez-Expósito; Miguel N Moreno-Carretero Journal: J Inorg Biochem Date: 2008-10-10 Impact factor: 4.155
Authors: Jürgen Bernard; Eva-Maria Köck; Roland G Huber; Klaus R Liedl; Ludwig Call; Robert Schlögl; Hinrich Grothe; Thomas Loerting Journal: RSC Adv Date: 2017-04-21 Impact factor: 3.361