Literature DB >> 16841972

Microwave-assisted synthesis of 3,1,2- and 2,1,8-Re(I) and 99mTc(I)-metallocarborane complexes.

Andrew E C Green1, Patrick W Causey, Anika S Louie, Andrea F Armstrong, Laura E Harrington, John F Valliant.   

Abstract

Microwave heating was used to prepare eta5-rhenium carborane complexes in aqueous reaction media. For carboranes bearing sterically demanding substituents, isomerization of the cage from 3,1,2 to 2,1,8 derivatives occurred concomitantly with complexation. Microwave heating was equally effective at the tracer level using technetium-99m, affording access to a new class of synthons for designing novel molecular imaging agents.

Entities:  

Mesh:

Substances:

Year:  2006        PMID: 16841972     DOI: 10.1021/ic0605928

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  4 in total

1.  Microwave-Assisted Synthesis of Organometallic Rhenium (I) Pentylcarbonato Complexes: New Synthon for Carboxylato, Sulfonato and Chlorido Complexes.

Authors:  Angela J Winstead; Khayra Alabrash; Brent V Powell; Sabreea J Parnell; Tiara V Hinton; Tijesunimi Odebode; Jiangnan Peng; Jeanette A Krause; Peter Y Zavalij; Santosh K Mandal
Journal:  J Organomet Chem       Date:  2021-01-27       Impact factor: 2.369

2.  Permeability of the blood-brain barrier to a rhenacarborane.

Authors:  Patrick M Hawkins; Paul A Jelliss; Naoko Nonaka; Xiaoming Shi; William A Banks
Journal:  J Pharmacol Exp Ther       Date:  2009-01-29       Impact factor: 4.030

3.  Separation of 44Sc from 44Ti in the Context of A Generator System for Radiopharmaceutical Purposes with the Example of [44Sc]Sc-PSMA-617 and [44Sc]Sc-PSMA-I&T Synthesis.

Authors:  Anton A Larenkov; Artur G Makichyan; Vladimir N Iatsenko
Journal:  Molecules       Date:  2021-10-21       Impact factor: 4.411

Review 4.  Microwave-Assisted Synthesis: Can Transition Metal Complexes Take Advantage of This "Green" Method?

Authors:  Elisabetta Gabano; Mauro Ravera
Journal:  Molecules       Date:  2022-06-30       Impact factor: 4.927

  4 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.