Recent Advances of Triazine-Based Materials for Adsorbent Based Extraction Techniques.

This review mainly focused on the synthesis and properties of triazine-based materials as well as the state-of-the-art development of these materials in adsorption-based extraction techniques in the past 5 years, such as solid-phase extraction, magnetic solid-phase extraction, solid-phase microextraction and stir bar sorptive extraction, and the detection of various pollutants, including metal ions, drugs, estrogens, nitroaromatics, pesticides, phenols, polycyclic aromatic hydrocarbons and parabens. In the triazine-functionalized composites, triazine-based polymers and covalent triazine frameworks have been developed as the adsorbents with potential for environmental pollutants, mainly relying on the large surface area and the affinity of triazinyl groups with the targets. Triazine-based adsorbents have satisfactory sensitivity and selectivity towards different types of analytes, attributed from various mechanisms including π-π, electrostatics, hydrogen bonds, and hydrophobic and hydrophilic effects. The prospects of the materials for adsorption-based extraction were also presented, which can offer an outlook for the further development and applications.