Literature DB >> 33936762

Crystallographic characterization of (C5H4SiMe3)3U(BH4).

Cory J Windorff1,2, Justin N Cross1, Brian L Scott1, Stosh A Kozimor1, William J Evans2.   

Abstract

New syntheses have been developed for the synthesis of (borohydrido-κ3 H)tris-[η5-(tri-methyl-sil-yl)cyclo-penta-dien-yl]uranium(IV), [U(BH4)(C8H13Si)3] or Cp'3U(BH4) (Cp' = C5H4SiMe3) and its structure has been determined by single-crystal X-ray crystallography. This compound crystallized in the space group P and the structure features three η 5-coordinated Cp' rings and a κ 3-coordinated (BH4)- ligand. © Windorff et al. 2021.

Entities:  

Keywords:  borohydride; crystal structure; cyclo­penta­dienyl compounds; uranium

Year:  2021        PMID： 33936762      PMCID： PMC8025856          DOI： 10.1107/S2056989021002425

Source DB:  PubMed          Journal:  Acta Crystallogr E Crystallogr Commun


  14 in total

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Journal:  Acta Crystallogr B       Date:  2001-01-24

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Authors:  George M Sheldrick
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Journal:  Chem Commun (Camb)       Date:  2009-12-03       Impact factor: 6.222

5.  Activation of carbon suboxide (C3O2) by U(iii) to form a cyclobutane-1,3-dione ring.

Authors:  Nikolaos Tsoureas; F Geoffrey N Cloke
Journal:  Chem Commun (Camb)       Date:  2018-08-07       Impact factor: 6.222

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Authors:  Justin C Wedal; Samuel Bekoe; Joseph W Ziller; Filipp Furche; William J Evans
Journal:  Dalton Trans       Date:  2019-10-29       Impact factor: 4.390

7.  Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination.

Authors:  Lennard Krause; Regine Herbst-Irmer; George M Sheldrick; Dietmar Stalke
Journal:  J Appl Crystallogr       Date:  2015-01-30       Impact factor: 3.304

8.  Crystal structure refinement with SHELXL.

Authors:  George M Sheldrick
Journal:  Acta Crystallogr C Struct Chem       Date:  2015-01-01       Impact factor: 1.172

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Authors:  Colin R Groom; Ian J Bruno; Matthew P Lightfoot; Suzanna C Ward
Journal:  Acta Crystallogr B Struct Sci Cryst Eng Mater       Date:  2016-04-01
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