Literature DB >> 20066307

Uranium-hydrogen interactions: synthesis and crystal structures of tris(N,N-dimethylaminodiboranato)uranium(III).

Scott R Daly1, Gregory S Girolami.   

Abstract

The reaction of UCl(4) with Na(H(3)BNMe(2)BH(3)) in diethyl ether affords the uranium(III) product U(H(3)BNMe(2)BH(3))(3), which has been crystallized in two different structural isomers depending on the crystallization solvent. Both forms are polymeric, but the nature of the bridging interaction is different in the two forms.

Entities:  

Year:  2009        PMID: 20066307     DOI: 10.1039/b919490h

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Crystallographic characterization of (C5H4SiMe3)3U(BH4).

Authors:  Cory J Windorff; Justin N Cross; Brian L Scott; Stosh A Kozimor; William J Evans
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2021-03-12
  1 in total

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