Literature DB >> 33859442

Regioselective Arylboration of 1,3-Butadiene.

Allison M Bergmann1, Stephen R Sardini1, Kevin B Smith1, M Kevin Brown1.   

Abstract

A method for the regioselective 1,2-arylboration of 1,3-butadiene, a feedstock chemical, is reported. The reactions result in the formation of products that can be easily elaborated to other structures. The mechanistic details of this process are also discussed.

Entities:  

Keywords:  Arylboration; Boron; Copper; Diene; Palladium

Year:  2019        PMID： 33859442      PMCID： PMC8046179          DOI： 10.1002/ijch.201900060

Source DB:  PubMed          Journal:  Isr J Chem        ISSN： 0021-2148            Impact factor:   3.333


  4 in total

1.  Cooperative Pd/Cu Catalysis for Alkene Arylboration: Opportunities for Divergent Reactivity.

Authors:  Stanna K Dorn; M Kevin Brown
Journal:  ACS Catal       Date:  2022-01-24       Impact factor: 13.700

2.  Catalytic Arylboration of Spirocyclic Cyclobutenes: Rapid Access to Highly Substituted Spiro[3.n]alkanes.

Authors:  Amit Kumar Simlandy; Mao-Yun Lyu; M Kevin Brown
Journal:  ACS Catal       Date:  2021-10-06       Impact factor: 13.700

3.  Modular Synthesis of a Versatile Double-Allylation Reagent for Complex Diol Synthesis.

Authors:  Stanna K Dorn; Annika E Tharp; M Kevin Brown
Journal:  Angew Chem Int Ed Engl       Date:  2021-06-11       Impact factor: 16.823

4.  Cyclic (Alkyl)(amino)carbene Ligands Enable Cu-Catalyzed Markovnikov Protoboration and Protosilylation of Terminal Alkynes: A Versatile Portal to Functionalized Alkenes*.

Authors:  Yang Gao; Sima Yazdani; Aaron Kendrick; Glen P Junor; Taeho Kang; Douglas B Grotjahn; Guy Bertrand; Rodolphe Jazzar; Keary M Engle
Journal:  Angew Chem Int Ed Engl       Date:  2021-07-29       Impact factor: 16.823
  4 in total

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