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Literature DB >> 36212545

Cooperative Pd/Cu Catalysis for Alkene Arylboration: Opportunities for Divergent Reactivity.

Abstract

A preeminent challenge in alkene difunctionalization is the control of regio-, diastereo-, and enantioselectivity. In this Perspective, a Pd/Cu-cooperative catalytic system for alkene arylboration is highlighted that allows for the controlled introduction of substituents. In particular, examples that allowed for divergent reactivity from a single substrate based on the tuning of catalysts and reaction conditions are emphasized.

Entities: Chemical

Keywords: arylboration; boron; cooperative catalysis; copper; palladium

Year: 2022 PMID： 36212545 PMCID： PMC9540610 DOI： 10.1021/acscatal.1c05696

Source DB: PubMed Journal: ACS Catal Impact factor: 13.700

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References

43 in total

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Authors: Zhen Liu; Yang Gao; Tian Zeng; Keary M Engle
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Authors: Kaitlyn M Logan; Stephen R Sardini; Sean D White; M Kevin Brown
Journal: J Am Chem Soc Date: 2017-12-22 Impact factor: 15.419

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Authors: Filippo Romiti; Juan Del Pozo; Paulo H S Paioti; Stella A Gonsales; Xinghan Li; Felix W W Hartrampf; Amir H Hoveyda
Journal: J Am Chem Soc Date: 2019-11-01 Impact factor: 15.419

Cooperative Pd/Cu Catalysis for Alkene Arylboration: Opportunities for Divergent Reactivity.

1. Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.

2. Copper/palladium synergistic catalysis for the syn- and anti-selective carboboration of alkenes.

3. Transition-Metal-Catalyzed 1,2-Carboboration of Alkenes: Strategies, Mechanisms, and Stereocontrol.

4. Nickel-Catalyzed Stereoselective Arylboration of Unactivated Alkenes.

5. Different Strategies for Designing Dual-Catalytic Enantioselective Processes: From Fully Cooperative to Non-cooperative Systems.

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8. Synergistic Dual Transition Metal Catalysis.

9. Biaryl Monophosphine Ligands in Palladium-Catalyzed C-N Coupling: An Updated User's Guide.

Review 10. Recent developments in nickel-catalyzed intermolecular dicarbofunctionalization of alkenes.