High-Energy Metal-Organic Frameworks with a Dicyanamide Linker for Hypergolic Fuels.

In this study, a hypergolic linker (dicyanamide, DCA) and a high-energy nitrogen-rich ligand (1,5-diaminotetrazole, DAT) were applied to construct high-energy metal-organic frameworks (HEMOFs) with hypergolic property. Three novel metal-organic frameworks (MOFs) were synthesized via a mild method with fascinating 2D polymeric architectures, and they could ignite spontaneously upon contact with white fuming nitric acid (WFNA). The gravimetric energy densities of the three HEMOFs all exceeded 26.2 kJ·g-1. The cupric MOF exhibits the highest gravimetric and volumetric energy density of 27.5 kJ·g-1 and 51.3 kJ·cm-3, respectively. By adjusting the metal cations, high-energy ligands and hypergolic linkers can improve the performance of hypergolic MOFs. This work provides a strategy for manufacturing MOFs as potential high-energy hypergolic fuels.