Bi Nanoparticles Embedded in 2D Carbon Nanosheets as an Interfacial Layer for Advanced Sodium Metal Anodes.

Sodium metal is regarded as one of the most prospective next-generation anodes material owing to its high theoretical capacity, low redox potential, low cost, and natural abundance. Its most notable problem is the dendrite growth during Na plating/striping, which causes not only the safety concern but also the generation of inactive Na. Here, it is demonstrated that 2D carbon nanosheets embedded by bismuth nanoparticles (NPs) (denoted as Bi⊂CNs) serve as a robust nucleation buffer layer to endow the sodium metal anodes (SMAs) with high Coulombic efficiencies (CEs) and dendrite-free deposition during long-term cycling. The embedded Bi nanoparticles significantly reduce the nucleation barrier through the "sodiophilic" Na-Bi alloy. Meanwhile, the carbon frameworks effectively circumvent the gradual failure of those Na-Bi nucleation sites. As a result, the metallic Na on the Bi⊂CNs nucleation layer is repeatedly plated/stripped for nearly 7700 h (1287 cycles) at 3 mA h cm-2 with an average CE of 99.92%. Moreover, the Na||Na symmetric cells with the Bi⊂CNs buffer layer are stably plated/stripped for 4000 h at 1 mA cm-2 and 1 mA h cm-2 . It is found that the cycling stability is closely related to the Na utilization of SMAs and current rate.