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Literature DB >> 33543174

Mechanochemical tools for polymer materials.

Yinjun Chen¹, Gaëlle Mellot, Diederik van Luijk, Costantino Creton, Rint P Sijbesma.

Abstract

Mechanochemistry provides a unique approach to investigate macroscopic deformation, failure and healing of polymer materials. The development of mechanophores - molecular units that respond to mechanical force - has been instrumental in the success of this endeavor. This review aims to provide a critical evaluation of the large variety of mechanophores reported in literature, and to assess the molecular and macroscopic factors that determine their activation. Applications in materials science are highlighted, and challenges in polymer mechanochemistry are discussed.

Entities: Chemical Disease

Year: 2021 PMID： 33543174 DOI： 10.1039/d0cs00940g

Source DB: PubMed Journal: Chem Soc Rev ISSN： 0306-0012 Impact factor: 54.564

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Cited

13 in total

1. Analyses of chemiluminescence reactions of fluorophore-linked 1,2-dioxetane isomers in crystals heating at elevated temperature including a development of a simultaneous measurement method of thermal diffusivity and light emission for a single crystal.

Authors: Chihiro Matsuhashi; Hiroki Fujisawa; Meguya Ryu; Tetsuya Tsujii; Shojiro Maki; Junko Morikawa; Takashi Hirano
Journal: Anal Sci Date: 2022-06-06 Impact factor: 1.967

Mechanochemical tools for polymer materials.

1. Analyses of chemiluminescence reactions of fluorophore-linked 1,2-dioxetane isomers in crystals heating at elevated temperature including a development of a simultaneous measurement method of thermal diffusivity and light emission for a single crystal.

Review 2. Tailoring the Properties of Optical Force Probes for Polymer Mechanochemistry.

3. The molecular mechanism of constructive remodeling of a mechanically-loaded polymer.

4. Bridging pico-to-nanonewtons with a ratiometric force probe for monitoring nanoscale polymer physics before damage.

5. Single-Molecule Force Spectroscopy of a Tetraaryl Succinonitrile Mechanophore.

Review 6. Action of Mechanical Forces on Polymerization and Polymers.

Review 7. The mechanochemical synthesis of polymers.

8. Mechanically Resistant Poly(N-vinylcaprolactam) Microgels with Sacrificial Supramolecular Catechin Hydrogen Bonds.

Review 9. The Mechanochemical Synthesis and Activation of Carbon-Rich π-Conjugated Materials.

Review 10. Release of Molecular Cargo from Polymer Systems by Mechanochemistry.