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Literature DB >> 33480147

Tetraimido Sulfuric Acid H₂ S(NtBu)₄ -Valence Isoelectronic to H₂ SO₄.

Jochen Jung¹, Annika Münch¹, Regine Herbst-Irmer¹, Dietmar Stalke¹.

Abstract

The valence isoelectronic imido analog H2 S(NtBu)4 (1) of sulfuric acid H2 SO4 was synthesized, isolated, and characterized by NMR spectroscopy and high-resolution X-ray charge density analysis. The latter reveals strongly polarized Sδ+ -Nδ- bonds with virtually no double bond character. The easy-to-polarize S-N bonds are an advantageous and versatile feature of sulfur nitrogen ligands, which enables them to adapt to different electron requirements of various metal cations.

Entities: Chemical Disease Species

Keywords: charge density; ligand design; metal coordination; structure determination; sulfur nitrogen ligands

Year: 2021 PMID： 33480147 PMCID： PMC7986191 DOI： 10.1002/anie.202014426

Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336

24 in total

1. Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite.

Authors: Thorsten Gehrmann; Matthias Kruck; Hubert Wadepohl; Lutz H Gade
Journal: Chem Commun (Camb) Date: 2012-01-25 Impact factor: 6.222

2. Triimidosulfonates as Acute Bite-Angle Chelates: Slow Relaxation of the Magnetization in Zero Field and Hysteresis Loop of a Co(II) Complex.

Authors: Elena Carl; Serhiy Demeshko; Franc Meyer; Dietmar Stalke
Journal: Chemistry Date: 2015-06-03 Impact factor: 5.236

Tetraimido Sulfuric Acid H₂ S(NtBu)₄ -Valence Isoelectronic to H₂ SO₄.

1. Stitching together SNx units in the coordination sphere of zirconium: assembly of a tris(imido)sulfite and a hydrazidobis(imido)sulfite.

2. Triimidosulfonates as Acute Bite-Angle Chelates: Slow Relaxation of the Magnetization in Zero Field and Hysteresis Loop of a Co(II) Complex.

3. Fundamental chemistry of binary S,N and ternary S,N,O anions: analogues of sulfur oxides and N,O anions.

4. Charge-density study of methane di(triimido)sulfonic acid H2C(S[(NtBu),(NHtbu)]2--the NR analogue of H2C[s(O)2(OH)]2.

5. Polyimido sulfur anions and ylides.

6. Bond paths are not chemical bonds.

7. ShelXle: a Qt graphical user interface for SHELXL.

8. Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination.

9. Crystal structure refinement with SHELXL.

10. S₆ N₂ O₁₅ -A Nitrogen-Poor Sulfur Nitride Oxide, and the Anhydride of Nitrido-tris-Sulfuric Acid.

1. Tetraimido Sulfuric Acid H₂ S(NtBu)₄ -Valence Isoelectronic to H₂ SO₄.

2. Isolation and Properties of the Long Elusive Deep Blue Soluble [K₃ {(N^t Bu)₃ S}₂ ]^. Cage Radical.

3. Alkali Metal Based Triimidosulfite Cages as Versatile Precursors for Single-Molecule Magnets.