Literature DB >> 33245197

Charge-Promoted Self-Metalation of Porphyrins on an Oxide Surface.

Larissa Egger1, Michael Hollerer1, Christian S Kern1, Hannes Herrmann1, Philipp Hurdax1, Anja Haags2,3,4, Xiaosheng Yang2,3,4, Alexander Gottwald5, Mathias Richter5, Serguei Soubatch2,3, F Stefan Tautz2,3,4, Georg Koller1, Peter Puschnig1, Michael G Ramsey1, Martin Sterrer1.   

Abstract

Metalation and self-metalation reactions of porphyrins on oxide surfaces have recently gained interest. The mechanism of porphyrin self-metalation on oxides is, however, far from being understood. Herein, we show by a combination of results obtained with scanning tunneling microscopy, photoemission spectroscopy, and DFT computations, that the self-metalation of 2H-tetraphenylporphyrin on the surface of ultrathin MgO(001) films is promoted by charge transfer. By tuning the work function of the MgO(001)/Ag(001) substrate, we are able to control the charge and the metalation state of the porphyrin molecules on the surface.
© 2020 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.

Entities:  

Keywords:  charge transfer; interfaces; metalation; porphyrins; thin films

Year:  2021        PMID： 33245197      PMCID： PMC7986846          DOI： 10.1002/anie.202015187

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   16.823


  19 in total

1.  Porphyrin Metalation at MgO Surfaces: A Spectroscopic and Quantum Mechanical Study on Complementary Model Systems.

Authors:  Johannes Schneider; Matthias Franke; Martin Gurrath; Michael Röckert; Thomas Berger; Johannes Bernardi; Bernd Meyer; Hans-Peter Steinrück; Ole Lytken; Oliver Diwald
Journal:  Chemistry       Date:  2015-12-18       Impact factor: 5.236

2.  Reconstruction of molecular orbital densities from photoemission data.

Authors:  Peter Puschnig; Stephen Berkebile; Alexander J Fleming; Georg Koller; Konstantin Emtsev; Thomas Seyller; John D Riley; Claudia Ambrosch-Draxl; Falko P Netzer; Michael G Ramsey
Journal:  Science       Date:  2009-09-10       Impact factor: 47.728

Review 3.  Porphyrins at interfaces.

Authors:  Willi Auwärter; David Écija; Florian Klappenberger; Johannes V Barth
Journal:  Nat Chem       Date:  2015-02       Impact factor: 24.427

4.  Porphyrin Metalation at the MgO Nanocube/Toluene Interface.

Authors:  Johannes Schneider; Fabian Kollhoff; Johannes Bernardi; Andre Kaftan; Jörg Libuda; Thomas Berger; Mathias Laurin; Oliver Diwald
Journal:  ACS Appl Mater Interfaces       Date:  2015-10-12       Impact factor: 9.229

5.  Interaction of free-base tetraphenylporphyrin with magnesium oxide: Influence of MgO morphology on metalation.

Authors:  Gianluca Di Filippo; Andrej Classen; Rebecca Pöschel; Thomas Fauster
Journal:  J Chem Phys       Date:  2017-02-14       Impact factor: 3.488

6.  Ordering aspects and intramolecular conformation of tetraphenylporphyrins on Ag(111).

Authors:  Florian Buchner; Ina Kellner; Wolfgang Hieringer; Andreas Görling; Hans-Peter Steinrück; Hubertus Marbach
Journal:  Phys Chem Chem Phys       Date:  2010-09-03       Impact factor: 3.676

7.  Controlled metalation of self-assembled porphyrin nanoarrays in two dimensions.

Authors:  Willi Auwärter; Alexander Weber-Bargioni; Susan Brink; Andreas Riemann; Agustin Schiffrin; Mario Ruben; Johannes V Barth
Journal:  Chemphyschem       Date:  2007-02-02       Impact factor: 3.102

8.  Surface-Mediated in Situ Metalation of Porphyrins at the Solid-Vacuum Interface.

Authors:  Hubertus Marbach
Journal:  Acc Chem Res       Date:  2015-08-26       Impact factor: 22.384

9.  Multi-orbital charge transfer at highly oriented organic/metal interfaces.

Authors:  Giovanni Zamborlini; Daniel Lüftner; Zhijing Feng; Bernd Kollmann; Peter Puschnig; Carlo Dri; Mirko Panighel; Giovanni Di Santo; Andrea Goldoni; Giovanni Comelli; Matteo Jugovac; Vitaliy Feyer; Claus Michael Schneider
Journal:  Nat Commun       Date:  2017-08-25       Impact factor: 14.919
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  3 in total

1.  Demonstrating the Impact of the Adsorbate Orientation on the Charge Transfer at Organic-Metal Interfaces.

Authors:  Thomas Georg Boné; Andreas Windischbacher; Marie S Sättele; Katharina Greulich; Larissa Egger; Thomas Jauk; Florian Lackner; Holger F Bettinger; Heiko Peisert; Thomas Chassé; Michael G Ramsey; Martin Sterrer; Georg Koller; Peter Puschnig
Journal:  J Phys Chem C Nanomater Interfaces       Date:  2021-04-27       Impact factor: 4.177

2.  Self-Metalation of Porphyrins at the Solid-Gas Interface.

Authors:  Francesco Armillotta; Enrico D'Incecco; Manuel Corva; Matus Stredansky; Jean-Jacques Gallet; Fabrice Bournel; Andrea Goldoni; Alberto Morgante; Erik Vesselli; Alberto Verdini
Journal:  Angew Chem Int Ed Engl       Date:  2021-11-09       Impact factor: 16.823

3.  Charge-Promoted Self-Metalation of Porphyrins on an Oxide Surface.

Authors:  Larissa Egger; Michael Hollerer; Christian S Kern; Hannes Herrmann; Philipp Hurdax; Anja Haags; Xiaosheng Yang; Alexander Gottwald; Mathias Richter; Serguei Soubatch; F Stefan Tautz; Georg Koller; Peter Puschnig; Michael G Ramsey; Martin Sterrer
Journal:  Angew Chem Int Ed Engl       Date:  2021-01-14       Impact factor: 16.823
  3 in total

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