Literature DB >> 32969105

Amino-Supported Palladium Catalyst for Chemo- and Stereoselective Domino Reactions.

Man-Bo Li1, Jie Yang2, Ying Yang1, Guo-Yong Xu1, Gen Luo1, Jianping Yang3, Jan-E Bäckvall2,4.   

Abstract

A solid amino-supported palladium catalyst is used in an oxidative domino reaction for the diastereoselective construction of alkyne-substituted cyclopentenol compounds. This heterogeneous catalyst exhibits high efficiency and excellent chemoselectivity, as well as good recyclability. The chemoselectivity of the domino reactions was readily controlled by switching the solvent and catalyst. Asymmetric syntheses and an oxidative carbocyclization-borylation reaction have also been developed based on the heterogeneous palladium catalyst.
© 2020 The Authors. Published by Wiley-VCH GmbH.

Entities:  

Keywords:  amines; cyclizations; heterogeneous catalysis; palladium; supported catalysts

Year:  2020        PMID： 32969105      PMCID： PMC7839730          DOI： 10.1002/anie.202011708

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   16.823


  29 in total

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4.  Small Pd nanoparticles supported in large pores of mesocellular foam: an excellent catalyst for racemization of amines.

Authors:  Mozaffar Shakeri; Cheuk-wai Tai; Emmanuelle Göthelid; Sven Oscarsson; Jan-E Bäckvall
Journal:  Chemistry       Date:  2011-10-20       Impact factor: 5.236

5.  Hybrid Palladium Nanoparticles for Direct Hydrogen Peroxide Synthesis: The Key Role of the Ligand.

Authors:  Giacomo M Lari; Begoña Puértolas; Masoud Shahrokhi; Núria López; Javier Pérez-Ramírez
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-16       Impact factor: 15.336

6.  Maduropeptin: an antitumor chromoprotein with selective protease activity and DNA cleaving properties.

Authors:  N Zein; W Solomon; K L Colson; D R Schroeder
Journal:  Biochemistry       Date:  1995-09-12       Impact factor: 3.162

7.  Palladium-Catalyzed Oxidative Carbocyclization-Borylation of Enallenes to Cyclobutenes.

Authors:  Youai Qiu; Bin Yang; Can Zhu; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2016-04-18       Impact factor: 15.336

8.  Highly Efficient Cascade Reaction for Selective Formation of Spirocyclobutenes from Dienallenes via Palladium-Catalyzed Oxidative Double Carbocyclization-Carbonylation-Alkynylation.

Authors:  Youai Qiu; Bin Yang; Can Zhu; Jan-E Bäckvall
Journal:  J Am Chem Soc       Date:  2016-10-13       Impact factor: 15.419

9.  Efficient Stereoselective Carbocyclization to cis-1,4-Disubstituted Heterocycles Enabled by Dual Pd/Electron Transfer Mediator (ETM) Catalysis.

Authors:  Can Zhu; Jie Liu; Binh Khanh Mai; Fahmi Himo; Jan-E Bäckvall
Journal:  J Am Chem Soc       Date:  2020-03-13       Impact factor: 15.419

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Authors:  Karin Engström; Eric V Johnston; Oscar Verho; Karl P J Gustafson; Mozaffar Shakeri; Cheuk-Wai Tai; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2013-11-12       Impact factor: 15.336
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