Literature DB >> 32573218

Regioselective, Photocatalytic α-Functionalization of Amines.

Lingying Leng1, Yue Fu2, Peng Liu2, Joseph M Ready1.   

Abstract

Photocatalytic α-functionalization of amines provides a mild and atom-economical means to synthesize α-branched amines. Prior examples featured symmetrical or electronically biased substrates. Here we report a controllable α-functionalization of amines in which regioselectivity can be tuned with minor changes to the reaction conditions.

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Year:  2020        PMID： 32573218     DOI： 10.1021/jacs.0c03758

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  6 in total

1.  Site-Selective α-C-H Functionalization of Trialkylamines via Reversible Hydrogen Atom Transfer Catalysis.

Authors:  Yangyang Shen; Ignacio Funez-Ardoiz; Franziska Schoenebeck; Tomislav Rovis
Journal:  J Am Chem Soc       Date:  2021-11-05       Impact factor: 15.419

2.  Aerobic Oxidative EDA Catalysis: Synthesis of Tetrahydroquinolines Using an Organocatalytic EDA Active Acceptor.

Authors:  August Runemark; Henrik Sundén
Journal:  J Org Chem       Date:  2022-01-10       Impact factor: 4.354

3.  Photocatalytic Hydroaminoalkylation of Styrenes with Unprotected Primary Alkylamines.

Authors:  Hannah E Askey; James D Grayson; Joshua D Tibbetts; Jacob C Turner-Dore; Jake M Holmes; Gabriele Kociok-Kohn; Gail L Wrigley; Alexander J Cresswell
Journal:  J Am Chem Soc       Date:  2021-09-20       Impact factor: 15.419

4.  Stereoselective Synthesis of Tertiary Allylic Amines by Titanium-Catalyzed Hydroaminoalkylation of Alkynes with Tertiary Amines.

Authors:  Tobias Kaper; Dennis Geik; Felix Fornfeist; Marc Schmidtmann; Sven Doye
Journal:  Chemistry       Date:  2022-01-25       Impact factor: 5.020

5.  Regio-, Diastereo-, and Enantioselective Decarboxylative Hydroaminoalkylation of Dienol Ethers Enabled by Dual Palladium/Photoredox Catalysis.

Authors:  Jun Zheng; Nana Tang; Hui Xie; Bernhard Breit
Journal:  Angew Chem Int Ed Engl       Date:  2022-03-16       Impact factor: 16.823

6.  Synthesis of N-aryl amines enabled by photocatalytic dehydrogenation.

Authors:  Jungwon Kim; Siin Kim; Geunho Choi; Geun Seok Lee; Donghyeok Kim; Jungkweon Choi; Hyotcherl Ihee; Soon Hyeok Hong
Journal:  Chem Sci       Date:  2020-12-08       Impact factor: 9.825
  6 in total

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