Literature DB >> 32499438

Nontargeted mass-spectral detection of chloroperfluoropolyether carboxylates in New Jersey soils.

John W Washington1, Charlita G Rosal2, James P McCord3, Mark J Strynar3, Andrew B Lindstrom3, Erica L Bergman4, Sandra M Goodrow5, Haile K Tadesse3, Andrew N Pilant3, Benjamin J Washington6, Mary J Davis2, Brittany G Stuart7, Thomas M Jenkins8.   

Abstract

The toxicity and environmental persistence of anthropogenic per- and poly-fluoroalkyl substances (PFAS) are of global concern. To address legacy PFAS concerns in the United States, industry developed numerous replacement PFAS that commonly are treated as confidential information. To investigate the distribution of PFAS in New Jersey, soils collected from across the state were subjected to nontargeted mass-spectral analyses. Ten chloroperfluoropolyether carboxylates were tentatively identified, with at least three congeners in all samples. Nine congeners are ≥(CF2)7 Distinct chemical formulas and structures, as well as geographic distribution, suggest airborne transport from an industrial source. Lighter congeners dispersed more widely than heavier congeners, with the most widely dispersed detected in an in-stock New Hampshire sample. Additional data were used to develop a legacy-PFAS fingerprint for historical PFAS sources in New Jersey.
Copyright © 2020 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works.

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Year:  2020        PMID: 32499438      PMCID: PMC7814412          DOI: 10.1126/science.aba7127

Source DB:  PubMed          Journal:  Science        ISSN: 0036-8075            Impact factor:   47.728


  22 in total

1.  Identification of Unsaturated and 2H Polyfluorocarboxylate Homologous Series and Their Detection in Environmental Samples and as Polymer Degradation Products.

Authors:  John W Washington; Thomas M Jenkins; Eric J Weber
Journal:  Environ Sci Technol       Date:  2015-11-05       Impact factor: 9.028

Review 2.  Biological monitoring of polyfluoroalkyl substances: A review.

Authors:  Magali Houde; Jonathan W Martin; Robert J Letcher; Keith R Solomon; Derek C G Muir
Journal:  Environ Sci Technol       Date:  2006-06-01       Impact factor: 9.028

3.  Perfluorinated compounds in aquatic organisms at various trophic levels in a Great Lakes food chain.

Authors:  Kurunthachalam Kannan; Lin Tao; Ewan Sinclair; Stephanie D Pastva; Dave J Jude; John P Giesy
Journal:  Arch Environ Contam Toxicol       Date:  2005-05       Impact factor: 2.804

4.  Decades-scale degradation of commercial, side-chain, fluorotelomer-based polymers in soils and water.

Authors:  John W Washington; Thomas M Jenkins; Keegan Rankin; Jonathan E Naile
Journal:  Environ Sci Technol       Date:  2015-01-20       Impact factor: 9.028

5.  Global distribution of perfluorooctane sulfonate in wildlife.

Authors:  J P Giesy; K Kannan
Journal:  Environ Sci Technol       Date:  2001-04-01       Impact factor: 9.028

6.  Use of carbon isotopic ratios in nontargeted analysis to screen for anthropogenic compounds in complex environmental matrices.

Authors:  John W Washington; Charlita G Rosal; Elin M Ulrich; Thomas M Jenkins
Journal:  J Chromatogr A       Date:  2018-11-11       Impact factor: 4.759

7.  Degradation of fluorotelomer alcohols: a likely atmospheric source of perfluorinated carboxylic acids.

Authors:  David A Ellis; Jonathan W Martin; Amila O De Silva; Scott A Mabury; Michael D Hurley; Mads P Sulbaek Andersen; Timothy J Wallington
Journal:  Environ Sci Technol       Date:  2004-06-15       Impact factor: 9.028

Review 8.  The developmental toxicity of perfluoroalkyl acids and their derivatives.

Authors:  Christopher Lau; John L Butenhoff; John M Rogers
Journal:  Toxicol Appl Pharmacol       Date:  2004-07-15       Impact factor: 4.219

9.  Determining global background soil PFAS loads and the fluorotelomer-based polymer degradation rates that can account for these loads.

Authors:  John W Washington; Keegan Rankin; E Laurence Libelo; David G Lynch; Mike Cyterski
Journal:  Sci Total Environ       Date:  2018-10-10       Impact factor: 7.963

10.  Proposed minimum reporting standards for chemical analysis Chemical Analysis Working Group (CAWG) Metabolomics Standards Initiative (MSI).

Authors:  Lloyd W Sumner; Alexander Amberg; Dave Barrett; Michael H Beale; Richard Beger; Clare A Daykin; Teresa W-M Fan; Oliver Fiehn; Royston Goodacre; Julian L Griffin; Thomas Hankemeier; Nigel Hardy; James Harnly; Richard Higashi; Joachim Kopka; Andrew N Lane; John C Lindon; Philip Marriott; Andrew W Nicholls; Michael D Reily; John J Thaden; Mark R Viant
Journal:  Metabolomics       Date:  2007-09       Impact factor: 4.290

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  16 in total

1.  Emerging Chlorinated Polyfluorinated Polyether Compounds Impacting the Waters of Southwestern New Jersey Identified by Use of Nontargeted Analysis.

Authors:  James P McCord; Mark J Strynar; John W Washington; Erica L Bergman; Sandra M Goodrow
Journal:  Environ Sci Technol Lett       Date:  2020-12-08

2.  Structure Database and In Silico Spectral Library for Comprehensive Suspect Screening of Per- and Polyfluoroalkyl Substances (PFASs) in Environmental Media by High-resolution Mass Spectrometry.

Authors:  Gordon J Getzinger; Christopher P Higgins; P Lee Ferguson
Journal:  Anal Chem       Date:  2021-01-26       Impact factor: 6.986

Review 3.  Understanding the dynamics of physiological changes, protein expression, and PFAS in wildlife.

Authors:  Jacqueline Bangma; T C Guillette; Paige A Bommarito; Carla Ng; Jessica L Reiner; Andrew B Lindstrom; Mark J Strynar
Journal:  Environ Int       Date:  2021-12-09       Impact factor: 9.621

4.  Uncovering global-scale risks from commercial chemicals in air.

Authors:  Qifan Liu; Li Li; Xianming Zhang; Amandeep Saini; Wenlong Li; Hayley Hung; Chunyan Hao; Kun Li; Patrick Lee; Jeremy J B Wentzell; Chunyan Huo; Shao-Meng Li; Tom Harner; John Liggio
Journal:  Nature       Date:  2021-12-15       Impact factor: 49.962

5.  Environmental Fate of Cl-PFPECAs: Predicting the Formation of PFAS Transformation Products in New Jersey Soils.

Authors:  Marina G Evich; Mary Davis; Eric J Weber; Caroline Tebes-Stevens; Brad Acrey; William Matthew Henderson; Sandra Goodrow; Erica Bergman; John W Washington
Journal:  Environ Sci Technol       Date:  2022-05-26       Impact factor: 11.357

6.  Are Fluoropolymers Really of Low Concern for Human and Environmental Health and Separate from Other PFAS?

Authors:  Rainer Lohmann; Ian T Cousins; Jamie C DeWitt; Juliane Glüge; Gretta Goldenman; Dorte Herzke; Andrew B Lindstrom; Mark F Miller; Carla A Ng; Sharyle Patton; Martin Scheringer; Xenia Trier; Zhanyun Wang
Journal:  Environ Sci Technol       Date:  2020-10-12       Impact factor: 9.028

Review 7.  Per- and polyfluoroalkyl substances in the environment.

Authors:  Marina G Evich; Mary J B Davis; James P McCord; Brad Acrey; Jill A Awkerman; Detlef R U Knappe; Andrew B Lindstrom; Thomas F Speth; Caroline Tebes-Stevens; Mark J Strynar; Zhanyun Wang; Eric J Weber; W Matthew Henderson; John W Washington
Journal:  Science       Date:  2022-02-04       Impact factor: 47.728

8.  Per- and polyfluoroalkyl substances exposure science: current knowledge, information needs, future directions.

Authors:  B Cheng; K Alapaty; V Zartarian; A Poulakos; M Strynar; T Buckley
Journal:  Int J Environ Sci Technol (Tehran)       Date:  2021-11-03       Impact factor: 2.860

9.  Characterizing the Air Emissions, Transport, and Deposition of Per- and Polyfluoroalkyl Substances from a Fluoropolymer Manufacturing Facility.

Authors:  Emma L D'Ambro; Havala O T Pye; Jesse O Bash; James Bowyer; Chris Allen; Christos Efstathiou; Robert C Gilliam; Lara Reynolds; Kevin Talgo; Benjamin N Murphy
Journal:  Environ Sci Technol       Date:  2021-01-04       Impact factor: 9.028

10.  Ideal versus Nonideal Transport of PFAS in Unsaturated Porous Media.

Authors:  Mark L Brusseau; Bo Guo; Dandan Huang; Ni Yan; Ying Lyu
Journal:  Water Res       Date:  2021-07-06       Impact factor: 13.400

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