Literature DB >> 32249989

Comment on "Realization of Lewis Basic Sodium Anion in the NaBH3 - Cluster".

Sudip Pan1,2, Gernot Frenking1,2.   

Abstract

We challenge the interpretation of the chemical bond in NaBH3 - proposed by Liu et al. We argue that NaBH3 - has an electron-sharing Na-BH3 - covalent bond rather than a dative bond Na- →BH3 .
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  bonding analysis; dative bonding; electron-sharing bonding; energy decomposition analysis

Year:  2020        PMID： 32249989     DOI： 10.1002/anie.202000229

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  7 in total

1.  Energy Decomposition Analysis Coupled with Natural Orbitals for Chemical Valence and Nucleus-Independent Chemical Shift Analysis of Bonding, Stability, and Aromaticity of Functionalized Fulvenes: A Bonding Insight.

Authors:  Sai Manoj N V T Gorantla; Kartik Chandra Mondal
Journal:  ACS Omega       Date:  2021-07-06

2.  Path-dependency of energy decomposition analysis & the elusive nature of bonding.

Authors:  Jordi Poater; Diego M Andrada; Miquel Solà; Cina Foroutan-Nejad
Journal:  Phys Chem Chem Phys       Date:  2022-01-26       Impact factor: 3.676

3.  Bonding and stability of donor ligand-supported heavier analogues of cyanogen halides (L')PSi(X)(L).

Authors:  Sai Manoj N V T Gorantla; Maria Francis; Sudipta Roy; Kartik Chandra Mondal
Journal:  RSC Adv       Date:  2021-02-10       Impact factor: 3.361

4.  Estimations of Fe0/-1-N2 interaction energies of iron(0)-dicarbene and its reduced analogue by EDA-NOCV analyses: crucial steps in dinitrogen activation under mild conditions.

Authors:  Sai Manoj N V T Gorantla; Kartik Chandra Mondal
Journal:  RSC Adv       Date:  2022-01-26       Impact factor: 3.361

5.  Bonding and stability of dinitrogen-bonded donor base-stabilized Si(0)/Ge(0) species [(cAACMe-Si/Ge)2(N2)]: EDA-NOCV analysis.

Authors:  Harsha S Karnamkkott; Sai Manoj N V T Gorantla; Kavita Devi; Geetika Tiwari; Kartik Chandra Mondal
Journal:  RSC Adv       Date:  2022-02-01       Impact factor: 3.361

6.  Collective interactions among organometallics are exotic bonds hidden on lab shelves.

Authors:  Shahin Sowlati-Hashjin; Vojtěch Šadek; SeyedAbdolreza Sadjadi; Mikko Karttunen; Angel Martín-Pendás; Cina Foroutan-Nejad
Journal:  Nat Commun       Date:  2022-04-19       Impact factor: 17.694

7.  Beyond the Classical Electron-Sharing and Dative Bond Picture: Case of the Spin-Polarized Bond.

Authors:  Pedro Salvador; Eva Vos; Inés Corral; Diego M Andrada
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-11       Impact factor: 15.336
  7 in total

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