Literature DB >> 32023069

Magnesium-Catalyzed Stereoselective Hydrostannylation of Internal and Terminal Alkynes.

Marc Magre1, Marcin Szewczyk1, Magnus Rueping1,2.   

Abstract

A regio- and stereoselective magnesium-catalyzed hydrostannylation of internal and terminal alkynes has been developed. Excellent yields and selectivities are obtained for a wide range of terminal and internal symmetrical and unsymmetrical alkynes by using this alkaline earth metal catalyst as an effective alternative to transition metal catalysts.

Entities:  

Year:  2020        PMID: 32023069     DOI: 10.1021/acs.orglett.0c00184

Source DB:  PubMed          Journal:  Org Lett        ISSN: 1523-7052            Impact factor:   6.005


  4 in total

Review 1.  s-Block Metal Catalysts for the Hydroboration of Unsaturated Bonds.

Authors:  Marc Magre; Marcin Szewczyk; Magnus Rueping
Journal:  Chem Rev       Date:  2022-03-07       Impact factor: 72.087

Review 2.  Recent advances in transition metal-free catalytic hydroelementation (E = B, Si, Ge, and Sn) of alkynes.

Authors:  Vitthal B Saptal; Ruibin Wang; Sehoon Park
Journal:  RSC Adv       Date:  2020-12-07       Impact factor: 4.036

3.  Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C-O Bond Activation.

Authors:  Marc Magre; Eva Paffenholz; Bholanath Maity; Luigi Cavallo; Magnus Rueping
Journal:  J Am Chem Soc       Date:  2020-08-04       Impact factor: 15.419

Review 4.  Generation of organo-alkaline earth metal complexes from non-polar unsaturated molecules and their synthetic applications.

Authors:  Kohei Watanabe; Jia Hao Pang; Ryo Takita; Shunsuke Chiba
Journal:  Chem Sci       Date:  2021-11-19       Impact factor: 9.825

  4 in total

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