Morphology-Independent Efficient Singlet Exciton Fission in Perylene Diimide Thin Films.

Perylene diimides are conjugated chromophores that are of considerable interest owing to their ability to transform a singlet excited state into two triplets by singlet fission. Although singlet fission has previously been reported for certain perylene diimide derivatives, there is some uncertainty about the rates and yield of the process in these materials. In this report, ultrafast transient absorption spectroscopy is used to demonstrate that singlet fission in perylene diimides can occur on a sub-picosecond timescale with quantum yields approaching the theoretical limit of 200 %.