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Literature DB >> 31763627

Functionalized 2,2'-Bipyrroles: Building Blocks for Pyrrolic Macrocycles.

Gonzalo Anguera^1,2, James T Brewster¹, David Sánchez-García², Jonathan L Sessler¹.

Abstract

Functionalized N-unsubstituted 2,2'-bipyrroles are basic building blocks for the preparation of pyrrolic macrocycles and natural products, such as prodigiosines. The aim of this review is to provide a description of the most important methodologies used to prepare 2,2'-bipyrroles and their central role as building blocks for the synthesis of porphyrinoids and property-defining structural elements therein.

Entities: Chemical Disease Gene Species

Keywords: 2,2’-Bipyrroles; expanded porphyrins; macrocycles; oligopyrroles

Year: 2018 PMID： 31763627 PMCID： PMC6874110 DOI： 10.6060/mhc180483s

Source DB: PubMed Journal: Macroheterocycles Impact factor: 1.200

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References

49 in total

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Authors: G Richard Geier; Scott C Grindrod
Journal: J Org Chem Date: 2004-09-17 Impact factor: 4.354

10. Porphyrin synthesis in water provides new expanded porphyrins with direct bipyrrole linkages: isolation and characterization of two heptaphyrins.

Authors: Satoru Hiroto; Hiroshi Shinokubo; Atsuhiro Osuka
Journal: J Am Chem Soc Date: 2006-05-24 Impact factor: 15.419

Functionalized 2,2'-Bipyrroles: Building Blocks for Pyrrolic Macrocycles.

1. Meso-substituted [34]octaphyrin(1.1.1.0.1.1.1.0) and corrole formation in reactions of a dipyrromethanedicarbinol with 2,2'-bipyrrole.

Review 2. Synthesis of natural products containing the pyrrolic ring.

3. One-pot synthesis of substituted 2,2'-bipyrroles. A straightforward route to aryl porphycenes.

4. Straightforward acid-catalyzed synthesis of pyrrolyldipyrromethenes.

5. Melanin. I. Kinetics of the oxidative cyclization of dopa to dopachrome.

6. Naphthylbipyrrole-Containing Amethyrin Analogue: A New Ligand for the Uranyl (UO₂²⁺) Cation.

Review 7. Recent advances in the synthesis of pyrroles by multicomponent reactions.

8. Dinaphthoporphycenes: synthesis and nonlinear optical studies.

9. Stable 5,5'-Substituted 2,2'-Bipyrroles: Building Blocks for Macrocyclic and Materials Chemistry.

10. Porphyrin synthesis in water provides new expanded porphyrins with direct bipyrrole linkages: isolation and characterization of two heptaphyrins.