| Literature DB >> 31746858 |
Mahendra K Sharma1, Beate Neumann, Hans-Georg Stammler, Diego M Andrada, Rajendra S Ghadwal.
Abstract
The first terminal arsinidene complexes [{(NHC)C(Ph)}As]Fe(CO)4 (NHC = IPr = C{(NDipp)CH}25, Me-IPr = C{(NDipp)CMe}26; Dipp = 2,6-iPr2C6H3) with a two-coordinated arsenic atom have been reported as crystalline solids. Calculations suggest that 5 and 6 are electrophilic, which has been demonstrated by the reaction of 5 with an NHC nucleophile (IMe4), affording the Lewis adduct [{(IPr)C(Ph)}As(IMe4)]Fe(CO)4 (7) (IMe4 = C(NMeCMe)2).Entities:
Year: 2019 PMID： 31746858 DOI： 10.1039/c9cc08630g
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222