Literature DB >> 31729824

Efficient Heterogeneous Palladium-Catalyzed Oxidative Cascade Reactions of Enallenols to Furan and Oxaborole Derivatives.

Man-Bo Li1,2, Daniels Posevins1, Antoine Geoffroy1, Can Zhu1, Jan-E Bäckvall1.   

Abstract

A heterogeneous palladium-catalyzed oxidative cyclization of enallenols has been developed for the construction of highly substituted furan and oxaborole derivatives. The heterogeneous catalyst (Pd-AmP-MCF) exhibits high activity, high site- and stereoselectivity, and efficient palladium recyclability in the transformations.
© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Entities:  

Keywords:  efficiency; heterogeneous palladium; oxidative cyclizations; stereospecific

Year:  2019        PMID： 31729824     DOI： 10.1002/anie.201911462

Source DB:  PubMed          Journal:  Angew Chem Int Ed Engl        ISSN： 1433-7851            Impact factor:   15.336


  4 in total

1.  Iron-Catalyzed Contrasteric Functionalization of Allenic C(sp2)-H Bonds: Synthesis of α-Aminoalkyl 1,1-Disubstituted Allenes.

Authors:  Yidong Wang; Sarah G Scrivener; Xiao-Dong Zuo; Ruihan Wang; Philip N Palermo; Ethan Murphy; Austin C Durham; Yi-Ming Wang
Journal:  J Am Chem Soc       Date:  2021-09-07       Impact factor: 16.383

2.  Synthesis of oxaboranes via nickel-catalyzed dearylative cyclocondensation.

Authors:  Mason T Koeritz; Haley K Banovetz; Sean A Prell; Levi M Stanley
Journal:  Chem Sci       Date:  2022-05-20       Impact factor: 9.969

3.  Iron-Catalyzed Cross-Coupling of Propargyl Ethers with Grignard Reagents for the Synthesis of Functionalized Allenes and Allenols.

Authors:  Daniels Posevins; Aitor Bermejo-López; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2021-09-02       Impact factor: 16.823

4.  Amino-Supported Palladium Catalyst for Chemo- and Stereoselective Domino Reactions.

Authors:  Man-Bo Li; Jie Yang; Ying Yang; Guo-Yong Xu; Gen Luo; Jianping Yang; Jan-E Bäckvall
Journal:  Angew Chem Int Ed Engl       Date:  2020-11-10       Impact factor: 16.823
  4 in total

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