Crystal structure, Hirshfeld surface analysis and physicochemical characterization of bis-[4-(di-methyl-amino)-pyridinium] di-μ-chlorido-bis[di-chlorido-mercurate(II)].

The title mol-ecular salt, (C7H11N2)2[Hg2Cl6], crystallizes with two 4-(di-methyl-amino)-pyridinium cations (A and B) and two half hexa-chlorido-dimercurate(II) anions in the asymmetric unit. The organic cations exhibit essentially the same features with an almost planar pyridyl ring (r.m.s. deviations of 0.0028 and 0.0109 Å), which forms an inclined dihedral angle with the dimethyamino group [3.06 (1) and 1.61 (1)°, respectively]. The di-methyl-amino groups in the two cations are planar, and the C-N bond lengths are shorter than that in 4-(di-methyl-amino)-pyridine. In the crystal, mixed cation-anion layers lying parallel to the (010) plane are formed through N-H⋯Cl hydrogen bonds and adjacent layers are linked by C-H⋯Cl hydrogen bonds, forming a three-dimensional network. The analyses of the calculated Hirshfeld surfaces confirm the relevance of the above inter-molecular inter-actions, but also serve to further differentiate the weaker inter-molecular inter-actions formed by the organic cations and inorganic anions, such as π-π and Cl⋯Cl inter-actions. The powder XRD data confirms the phase purity of the crystalline sample. Furthermore, the vibrational absorption bands were identified by IR spectroscopy and the optical properties were studied by using optical UV-visible absorption spectroscopy. © Garci et al. 2019.

Chemical context

Hybrid organic–inorganic materials have been widely studied in recent years for their promising applications in different fields, including catalysis, magnetism and optics and for their luminescence properties (Clément et al., 1994 ▸; Rabu et al., 2001 ▸; Hu et al., 2003 ▸; Morris et al., 2008 ▸). However, owing to the confinement of the inorganic layers, the organic cations have to possess the right ionic bond and steric hindrance, as well as hydrogen bonds, to fit the coordination environment provided by the inorganic framework for stabilization of these organic–inorganic hybrid systems.

Hybrids based on mercury have been synthesized and characterized with simple, different techniques, thanks to their self-assembling character (Mitzi et al., 2001 ▸) and are very inter­esting both for fundamental physics exploration such as electronic confinement (Wei et al., 2015 ▸) or as low-dimensional magnetic systems (Fersi et al., 2015 ▸) and diversify the field of technological applications.

A number of chloro­mercurate(II) complexes have been shown to exhibit ferroelectric behaviour (Mitsui & Nakamura, 1990 ▸) and inter­est has focused on the mechanism of the ferroelectric–paraelectric phase transition (White, 1963 ▸; Körfer et al., 1988 ▸; Jiang et al., 1995 ▸; Liesegang et al., 1995 ▸) for which structural information is crucial. In addition, the ability of the anions in this class of compounds to exhibit a wide range of geometry, stoichiometry and connectivity has long been known (Grdenic, 1965 ▸). This flexibility is a result of the large volume and spherical charge distribution of the Hg2+ ion, which are a consequence of the filled 4f and 5d electron shells. Moreover, organic–inorganic materials with pyridine and its derivatives as template agents have led to the preparation of some materials with inter­esting physical properties (Aakeröy et al., 2000 ▸; Prince et al., 2003 ▸) and biological activities (Bossert et al., 1981 ▸; Wang et al., 1989 ▸).

As part of our continuing investigation of new hybrid compounds containing an organic cation and an inorganic anion such as CrO4 2− (Chebbi et al., 2000 ▸; Chebbi & Driss, 2001 ▸, 2002a ▸,b ▸, 2004 ▸), Cr2O7 2− (Chebbi et al., 2016 ▸, Ben Smail et al., 2017 ▸), NO3 − (Chebbi et al., 2014 ▸, 2018 ▸) and ClO4 − (Chebbi et al., 2017 ▸; Ben Jomaa et al., 2018 ▸), we report in this work the crystal structure, the Hirshfeld surface analysis and the physicochemical characterization of a new organic chloro­mercurate(II), (C7H11N2)2[Hg2Cl6] (I).

Structural commentary

The asymmetric unit of the title compound comprises two 4-(di­methyl­amino)­pyridinium cations (A and B), and two half [Hg2Cl6]2− anions (Fig. 1 ▸). The two independent [Hg2(1,2)Cl6]2− anions are found to adopt a centrosymmetric arrangement with terminal Cl1—Hg1—Cl3 and Cl4—Hg2—Cl5 angles of 141.4 (1)° and 141.7 (1)° respectively. Each anion appears to be a distorted edge-shared bi­tetra­hedron, similar to that reported by Larock et al. (1987 ▸), with its center of mass coincident with a crystallographic center of symmetry. The two independent Hg⋯Cl bridging distances are 2.539 (2) and 2.542 (2) Å, leading to a slightly asymmetric bridging system as has been found in most structures containing the [Hg2Cl6]2− moiety (Linden et al., 1999 ▸; Zabel et al., 2008 ▸). In each anion, the two terminal Hg—Cl bonds are quite short [Hg1—Cl1 = 2.371 (2) and Hg1—Cl3 = 2.380 (2) Å, Hg2—Cl4 = 2.367 (3) and Hg2—Cl5 = 2.392 (2) Å] with a Cl1—Hg1—Cl2 and Cl4—Hg2—Cl6 angles of 112.01 (9) and 112.72 (10)°, respectively. Assessment of the organic geometrical features shows that they exhibit essentially the same features with an almost planar pyridyl ring (r.m.s. deviation = 0.0028 and 0.0109 Å for C1A–C5A/N1A and C1B–C5B/N1B, respectively), which forms an inclined dihedral angle with the dimethyamino group [3.06 (1) and 1.61 (1)°, respectively]. The di­methyl­amino groups in the two cations are planar and the C—N bond lengths [1.357 (11) Å for A and 1.326 (11) Å for B] are shorter than that in 4-di­methyl­amino­pyridine [1.367 (2) Å; Ohms & Guth, 1984 ▸]. These findings indicate the presence of strong conjugation between the di­methyl­amino group and the pyridine ring. The C3A—N1A—C4A [121.2 (8)°] and C3B—N1B—C4B [119.8 (9)°] bond angles are wider than that in pyridine (116.94°; Sørensen et al., 1974 ▸), which indicates that the pyridine ring N atom is protonated. Examination of the C—C(N) distances and C—C—C (N), C—N—C angles in the 4-(di­methyl­amino)­pyridinium dications (A and B) shows no significant difference from those obtained in other organic materials associated with the same organic groups (Chao et al., 1977 ▸; Mustaqim et al., 2005 ▸).

Figure 1

The mol­ecular structure of (I). Atomic displacement parameters for the non-H atoms are drawn at the 50% probability level. Unlabelled atoms are related to labelled ones by the symmetry operation −x + 1, −y, −z + 2.

The experimental powder X-ray diffraction pattern of the title compound, (C7H11N2)2[Hg2Cl6] is in good agreement with that simulated (Fig. 2 ▸). This indicates the purity of the synthesized product and confirms the crystal data used.

Figure 2

Experimental and simulated powder XRD patterns of (I).

Supra­molecular features

In the crystal structure, mixed cation–anion layers lying parallel to the (010) plane are formed through N—H⋯Cl hydrogen bonds and adjacent layers are linked by C—H⋯Cl hydrogen bonds, forming a three-dimensional network (Table 1 ▸, Fig. 3 ▸). A mixed layer is formed by alternating of organic and inorganic columns parallel to the [100] direction (Fig. 4 ▸). The cations (A or B) inter­act via offset face-to-face π–π stacking inter­actions, leading to two types of organic columns formed by the cations (A or B) with centroid-centroid distances of 3.698 (2) and 3.982 (2) Å, respectively (Fig. 5 ▸) (Janiak, 2000 ▸; Ben Moussa et al., 2018 ▸). Similarly, the hexa­chlorido­dimercurate(II) anions are dispersed parallel to the a axis whose cohesion is ensured by Cl⋯Cl [3.652 (6) Å] and Hg⋯Cl [3.167 (7) Å] weak inter­actions (Sumanesh et al., 2016 ▸; Ben Moussa et al., 2019a ▸,b ▸; Fig. 6 ▸).

Table 1

Hydrogen-bond geometry (Å, °)

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N1A—H1A⋯Cl3	0.86	2.54	3.239 (8)	140
N1B—H1B⋯Cl5	0.86	2.46	3.195 (10)	145
C2B—H2B⋯Cl1i	0.93	2.82	3.634 (11)	147
C3A—H3A⋯Cl5	0.93	2.75	3.485 (11)	136

Symmetry code: (i) .

Figure 3

Structure of (I) viewed along the a axis showing the succession of mixed layers parallel to the (010) plane. The orange dotted lines indicate hydrogen bonds.

Figure 4

A view of the supra­molecular mixed layer in the ac plane of (I), showing the alternating organic and inorganic columns parallel to the [100] direction. The orange dotted lines indicate N—H⋯Cl hydrogen bonds.

Figure 5

π–π stacking inter­actions between the nearest aromatic organic cation neighbors into two types of organic columns (A or B).

Figure 6

Cl⋯Cl and Hg⋯Cl inter­actions between hexa­chlorido­dimercurate(II) anions dispersed parallel to the a axis in the inorganic column.

Vibrational study

The obtained FT–IR spectrum for the studied hexa­chlorido­dimercurate(II) salt is depicted in Fig. 7 ▸. Detailed assignment of all bands observed in the infrared spectrum of the 4-(di­methyl­amino)­pyridinium cation in the title compound is based on the comparison with other compounds associated to the same cation (Koleva et al., 2008 ▸; Hu et al., 2012 ▸). In the region of high frequencies, the bands at 3243, 3130, 3100, 2959 cm−1 are due to the stretching vibrations of the N—H and C—H bonds. The band at 1646 cm−1 is assigned to the N—H bending mode. The bands at 1557 and 1445 cm−1 are attributed to the C=C and C=N stretching modes of the pyridine ring. The absorption band located at 1212 cm−1 corresponds to the ν(C—N) and ν(C—C) modes. The band at 1056 cm−1 can be attributed to the δ(C—C) mode. The remaining bands in the range 1000 to 500 cm−1 are assigned to γ(C—C), γ(C—H) and γ(C—N) out-of-plane bending modes.

Figure 7

Infrared spectrum of (I).

Optical properties and frontier mol­ecular orbitals

Optical absorption (OA) measurement of the title compound was performed at ambient temperature in an ethanol solution (10−4 M). As shown in Fig. 8 ▸, the OA spectrum exhibits two distinct absorption bands around 213 and 278 nm assigned to the π→π* absorption bands of the 4-(di­methyl­amino)­pyridinium cations. Thus, the experimental band-gap energy obtained from the absorption edge wavelength is about 3.98 eV. This band-gap value indicates that the grown crystal exhibits semiconductor behavior (Rosencher & Vinter, 2002 ▸). The highest occupied mol­ecular orbital (HOMO) and the lowest unoccupied mol­ecular orbital (LUMO), known as frontier orbitals, obtained with a B3LYP/6-311G+(d,p) [H, C, N, Cl]–LANL2DZ [Hg] level calculation are illustrated in Fig. 9 ▸. The HOMO is mainly delocalized at the pyridine ring system. After excitation, the charge is localized on the hexa­chlorido­dimercurate(II) moieties, as depicted in the LUMO. The calculated HOMO–LUMO energy gap (4.26 eV) is shifted from the experimental value, which may be attributed to solvent effects, compared to the gas-phase calculation.

Figure 8

UV–vis spectrum of (I). The inset shows the experimental energy band gap obtained from the absorption edge wavelength.

Figure 9

HOMO–LUMO mol­ecular orbitals showing the ground to excited state electronic transitions for (I).

Hirshfeld surface analysis

A Hirshfeld surface analysis (Spackman & Jayatilaka, 2009 ▸) and the associated two-dimensional fingerprint plots (McKinnon et al., 2007 ▸) were performed with CrystalExplorer17 (Turner et al., 2017 ▸) to investigate the inter­molecular inter­actions in the title compound. Fig. 10 ▸ a illustrates the Hirshfeld surface mapped over d norm, which was plotted with a colour scale of −0.211 to 1.132 a.u. with a standard (high) surface resolution. The red spots highlight the inter­atomic contacts including the N—H⋯Cl and C—H⋯Cl hydrogen bonds.

Figure 10

View of the Hirshfeld surfaces for (I) mapped over (a) d norm and (b) shape-index, displaying the inter­molecular inter­actions.

The shape-index of the Hirshfeld surface is a tool to visualize the π–π stacking by the presence of adjacent red and blue triangles; if there are no adjacent red and/or blue triangles, then there are no π–π inter­actions. Fig.10b clearly suggests that π–π inter­actions are present in the title hexa­chlorido­dimercurate(II) salt.

Fig. 11 ▸ a shows the two-dimensional fingerprint of all contacts contributing to the Hirshfeld surface. In Fig. 11 ▸ b, with two symmetrical wings on the left and right sides illustrate the H⋯Cl/Cl⋯H inter­actions with a contribution of 49.5%. Fig. 11 ▸ c illustrates the two-dimensional fingerprint plot of (d i, d e) points related to H⋯H contacts, which represent a 24.9% contribution. Furthermore, there are Hg⋯Cl/Cl⋯Hg (7.1%; Fig. 11 ▸ d), C⋯C (3.6%; Fig. 11 ▸ e) and Cl⋯Cl (1.2%; Fig. 11 ▸ f) contacts. Fig. 12 ▸ shows the percentage contributions of the various contacts in the title structure.

Figure 11

Full two-dimensional fingerprint plots for (I), showing (a) all inter­actions, and delineated into (b) H⋯Cl/Cl⋯H, (c) H⋯H, (d) Hg⋯Cl/Cl⋯Hg, (e) C⋯C and (f) Cl⋯Cl inter­actions. The d i and d e values are the closest inter­nal and external distances (in Å) from a given point on the Hirshfeld surface.

Figure 12

Relative contribution (%) of various inter­molecular inter­actions to the Hirshfeld surface area.

Synthesis and crystallization

The title compound was synthesized by dissolving 2 mmol (241 mg) of 4-di­methyl­amino­pyridine 98% (Sigma–Aldrich) in an HCl 36–38% (Sigma–Aldrich) aqueous solution and 1 mmol (273 mg) of mercury(II) chloride HgCl2 (Merck) in ethanol in a molar ratio of 2:1. The mixture was then stirred for 2 h. The resulting aqueous solution was filtered and then evaporated at room temperature, which finally led to the growth of parallelepipedic colourless crystals after one day.

Refinement

Crystal data, data collection and structure refinement details are summarized in Table 2 ▸. H atoms were placed in calculated positions, with N—H = 0.86 Å and C—H = 0.93 or 0.96 Å. U iso(H) values were constrained to be 1.5U eq of the carrier atom for methyl H atoms, and 1.2U eq for the remaining H atoms. The (111) and (121) reflections were omitted owing to bad disagreement.

Table 2

Experimental details

Crystal data
Chemical formula	(C7H11N2)2[Hg2Cl6]
M r	860.23
Crystal system, space group	Triclinic, P
Temperature (K)	293
a, b, c (Å)	7.6558 (3), 11.8961 (5), 13.5853 (4)
α, β, γ (°)	82.950 (3), 76.072 (3), 76.339 (4)
V (Å3)	1164.07 (8)
Z	2
Radiation type	Mo Kα
μ (mm−1)	13.87
Crystal size (mm)	0.72 × 0.24 × 0.18
Data collection
Diffractometer	Enraf–Nonius CAD-4
Absorption correction	ψ scan (North et al., 1968 ▸)
T min, T max	0.53, 0.99
No. of measured, independent and observed [I > 2σ(I)] reflections	7139, 5875, 3913
R int	0.040
(sin θ/λ)max (Å−1)	0.671
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.055, 0.153, 1.03
No. of reflections	5875
No. of parameters	236
H-atom treatment	H-atom parameters constrained
Δρmax, Δρmin (e Å−3)	3.41, −3.00

Computer programs: CAD-4 EXPRESS (Duisenberg, 1992 ▸; Macíček & Yordanov, 1992 ▸), XCAD4 (Harms & Wocadlo, 1995 ▸), SHELXT2018 (Sheldrick, 2015a ▸), SHELXL2018 (Sheldrick, 2015b ▸), DIAMOND (Brandenburg, 2006 ▸), Mercury (Macrae et al., 2006 ▸), WinGX (Farrugia, 2012 ▸) and publCIF (Westrip, 2010 ▸).

Crystal structure: contains datablock(s) I. DOI: 10.1107/S2056989019013124/vm2222sup1.cif

Structure factors: contains datablock(s) I. DOI: 10.1107/S2056989019013124/vm2222Isup2.hkl

CCDC reference: 1911692

Additional supporting information: crystallographic information; 3D view; checkCIF report

(C7H11N2)2[Hg2Cl6]	Z = 2
Mr = 860.23	F(000) = 792
Triclinic, P1	Dx = 2.454 Mg m−3
a = 7.6558 (3) Å	Mo Kα radiation, λ = 0.71073 Å
b = 11.8961 (5) Å	Cell parameters from 25 reflections
c = 13.5853 (4) Å	θ = 10–15°
α = 82.950 (3)°	µ = 13.87 mm−1
β = 76.072 (3)°	T = 293 K
γ = 76.339 (4)°	Parallelepiped, colorless
V = 1164.07 (8) Å3	0.72 × 0.24 × 0.18 mm

Enraf–Nonius CAD-4 diffractometer	3913 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	Rint = 0.040
Graphite monochromator	θmax = 28.5°, θmin = 2.3°
ω/2θ scans	h = −10→2
Absorption correction: ψ scan (North et al., 1968)	k = −15→15
Tmin = 0.53, Tmax = 0.99	l = −18→18
7139 measured reflections	2 standard reflections every 120 reflections
5875 independent reflections	intensity decay: 1%

Refinement on F2	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F2 > 2σ(F2)] = 0.055	w = 1/[σ2(Fo2) + (0.0933P)2] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.153	(Δ/σ)max = 0.001
S = 1.03	Δρmax = 3.41 e Å−3
5875 reflections	Δρmin = −3.00 e Å−3
236 parameters	Extinction correction: SHELXL2018 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
0 restraints	Extinction coefficient: 0.0058 (5)

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

	x	y	z	Uiso*/Ueq
Hg1	0.73846 (6)	0.52983 (3)	0.96401 (3)	0.04867 (15)
Hg2	0.70787 (6)	0.02376 (3)	0.53548 (3)	0.05017 (16)
Cl3	0.7012 (4)	0.6752 (2)	0.82926 (18)	0.0507 (6)
Cl5	0.5562 (4)	0.1596 (2)	0.66140 (18)	0.0518 (6)
Cl2	0.4827 (3)	0.5982 (2)	1.11547 (17)	0.0489 (6)
Cl6	0.5814 (4)	0.1067 (2)	0.37887 (17)	0.0487 (5)
Cl1	0.9450 (4)	0.3586 (2)	1.0069 (2)	0.0507 (6)
Cl4	0.9497 (4)	−0.1420 (2)	0.5038 (2)	0.0544 (6)
N1B	0.3722 (13)	0.0129 (9)	0.8551 (6)	0.055 (2)
H1B	0.423341	0.022921	0.791911	0.067*
N1A	0.6907 (12)	0.5280 (8)	0.6462 (6)	0.047 (2)
H1A	0.665775	0.537818	0.710142	0.056*
N2B	0.1208 (12)	−0.0324 (7)	1.1557 (6)	0.0441 (18)
C1B	0.2047 (12)	−0.0182 (8)	1.0590 (6)	0.0359 (19)
C5B	0.2580 (14)	0.0880 (8)	1.0172 (8)	0.043 (2)
H5B	0.237846	0.149257	1.057848	0.051*
N2A	0.8004 (12)	0.4827 (8)	0.3413 (6)	0.047 (2)
C2A	0.7198 (13)	0.4105 (8)	0.5161 (8)	0.042 (2)
H2A	0.712530	0.340021	0.496158	0.050*
C4B	0.3388 (16)	0.0977 (10)	0.9166 (9)	0.058 (3)
H4B	0.372259	0.167244	0.889581	0.069*
C1A	0.7683 (12)	0.4958 (8)	0.4424 (6)	0.0352 (18)
C2B	0.2482 (14)	−0.1070 (9)	0.9916 (7)	0.043 (2)
H2B	0.223027	−0.179339	1.015900	0.052*
C3B	0.3261 (15)	−0.0884 (10)	0.8918 (8)	0.052 (3)
H3B	0.347796	−0.147079	0.848196	0.063*
C5A	0.7751 (14)	0.6032 (9)	0.4768 (8)	0.047 (2)
H5A	0.805230	0.663582	0.430389	0.056*
C4A	0.7372 (15)	0.6156 (9)	0.5779 (8)	0.050 (2)
H4A	0.742924	0.684838	0.600944	0.061*
C3A	0.6831 (14)	0.4271 (9)	0.6157 (7)	0.045 (2)
H3A	0.652280	0.368100	0.663649	0.054*
C7B	0.0765 (17)	0.0644 (11)	1.2239 (8)	0.061 (3)
H7Q	0.016344	0.039805	1.290807	0.091*
H7P	0.188302	0.085789	1.227041	0.091*
H7D	−0.003486	0.129990	1.197662	0.091*
C6B	0.0727 (16)	−0.1412 (10)	1.1987 (8)	0.058 (3)
H6Q	0.013266	−0.134628	1.269144	0.087*
H6D	−0.009493	−0.159869	1.162861	0.087*
H6P	0.182338	−0.201411	1.192574	0.087*
C7A	0.8505 (17)	0.5720 (11)	0.2661 (8)	0.063 (3)
H7I	0.867226	0.546304	0.199482	0.094*
H7J	0.754609	0.640812	0.274933	0.094*
H7K	0.963334	0.588643	0.273377	0.094*
C6A	0.8007 (17)	0.3711 (11)	0.3057 (8)	0.065 (3)
H6K	0.825473	0.376560	0.232724	0.097*
H6I	0.894286	0.311834	0.328549	0.097*
H6J	0.682564	0.351849	0.332384	0.097*

	U11	U22	U33	U12	U13	U23
Hg1	0.0531 (3)	0.0467 (2)	0.0452 (2)	−0.00220 (18)	−0.01806 (17)	−0.00119 (16)
Hg2	0.0507 (3)	0.0470 (3)	0.0479 (2)	−0.00196 (18)	−0.00822 (17)	−0.00665 (17)
Cl3	0.0702 (17)	0.0420 (12)	0.0451 (12)	−0.0111 (11)	−0.0240 (11)	−0.0015 (10)
Cl5	0.0602 (15)	0.0440 (13)	0.0483 (12)	−0.0159 (11)	0.0017 (11)	−0.0101 (10)
Cl2	0.0486 (13)	0.0604 (15)	0.0393 (11)	−0.0136 (11)	−0.0069 (10)	−0.0111 (10)
Cl6	0.0551 (14)	0.0543 (14)	0.0414 (11)	−0.0190 (11)	−0.0166 (10)	0.0044 (10)
Cl1	0.0547 (14)	0.0363 (11)	0.0709 (16)	−0.0105 (10)	−0.0348 (12)	0.0018 (11)
Cl4	0.0431 (13)	0.0373 (12)	0.0800 (18)	−0.0075 (10)	−0.0079 (12)	−0.0065 (11)
N1B	0.052 (5)	0.072 (7)	0.038 (4)	−0.005 (5)	−0.012 (4)	−0.002 (4)
N1A	0.057 (5)	0.053 (5)	0.034 (4)	−0.016 (4)	−0.011 (4)	−0.006 (4)
N2B	0.049 (5)	0.048 (5)	0.035 (4)	−0.012 (4)	−0.009 (3)	−0.004 (3)
C1B	0.030 (4)	0.043 (5)	0.035 (4)	0.002 (3)	−0.018 (3)	−0.002 (4)
C5B	0.049 (5)	0.028 (4)	0.050 (5)	−0.001 (4)	−0.018 (4)	0.000 (4)
N2A	0.041 (4)	0.067 (6)	0.033 (4)	−0.011 (4)	−0.007 (3)	−0.005 (4)
C2A	0.040 (5)	0.035 (5)	0.053 (5)	−0.006 (4)	−0.015 (4)	−0.007 (4)
C4B	0.050 (6)	0.047 (6)	0.072 (7)	−0.005 (5)	−0.021 (5)	0.017 (5)
C1A	0.031 (4)	0.042 (5)	0.034 (4)	−0.007 (4)	−0.013 (3)	0.001 (4)
C2B	0.046 (5)	0.044 (5)	0.043 (5)	−0.006 (4)	−0.019 (4)	−0.004 (4)
C3B	0.052 (6)	0.061 (7)	0.046 (5)	0.004 (5)	−0.019 (5)	−0.026 (5)
C5A	0.049 (6)	0.043 (5)	0.051 (6)	−0.013 (4)	−0.018 (5)	0.003 (4)
C4A	0.053 (6)	0.038 (5)	0.061 (6)	−0.004 (4)	−0.013 (5)	−0.014 (5)
C3A	0.046 (5)	0.048 (6)	0.041 (5)	−0.013 (4)	−0.008 (4)	0.004 (4)
C7B	0.061 (7)	0.080 (8)	0.042 (5)	−0.014 (6)	−0.008 (5)	−0.019 (5)
C6B	0.064 (7)	0.063 (7)	0.051 (6)	−0.019 (6)	−0.019 (5)	0.005 (5)
C7A	0.066 (7)	0.074 (8)	0.041 (5)	−0.013 (6)	−0.006 (5)	0.013 (5)
C6A	0.068 (8)	0.081 (9)	0.048 (6)	−0.014 (7)	−0.011 (5)	−0.020 (6)

Hg1—Cl1	2.371 (2)	C2A—C3A	1.344 (14)
Hg1—Cl3	2.380 (2)	C2A—C1A	1.386 (13)
Hg1—Cl2	2.539 (2)	C2A—H2A	0.9300
Hg1—Cl2i	2.975 (2)	C4B—H4B	0.9300
Hg2—Cl4	2.367 (3)	C1A—C5A	1.429 (13)
Hg2—Cl5	2.392 (2)	C2B—C3B	1.357 (15)
Hg2—Cl6	2.542 (2)	C2B—H2B	0.9300
Hg2—Cl6ii	2.934 (3)	C3B—H3B	0.9300
N1B—C4B	1.329 (15)	C5A—C4A	1.352 (15)
N1B—C3B	1.340 (15)	C5A—H5A	0.9300
N1B—H1B	0.8600	C4A—H4A	0.9300
N1A—C3A	1.334 (13)	C3A—H3A	0.9300
N1A—C4A	1.362 (14)	C7B—H7Q	0.9600
N1A—H1A	0.8600	C7B—H7P	0.9600
N2B—C1B	1.326 (12)	C7B—H7D	0.9600
N2B—C6B	1.445 (14)	C6B—H6Q	0.9600
N2B—C7B	1.492 (13)	C6B—H6D	0.9600
C1B—C2B	1.410 (13)	C6B—H6P	0.9600
C1B—C5B	1.429 (14)	C7A—H7I	0.9600
C5B—C4B	1.360 (15)	C7A—H7J	0.9600
C5B—H5B	0.9300	C7A—H7K	0.9600
N2A—C1A	1.357 (11)	C6A—H6K	0.9600
N2A—C7A	1.435 (14)	C6A—H6I	0.9600
N2A—C6A	1.468 (15)	C6A—H6J	0.9600
Cl1—Hg1—Cl3	141.44 (10)	C2A—C1A—C5A	117.1 (8)
Cl1—Hg1—Cl2	112.01 (9)	C3B—C2B—C1B	121.0 (10)
Cl3—Hg1—Cl2	106.16 (9)	C3B—C2B—H2B	119.5
Cl1—Hg1—Cl2i	93.63 (8)	C1B—C2B—H2B	119.5
Cl3—Hg1—Cl2i	88.63 (8)	N1B—C3B—C2B	121.1 (9)
Cl2—Hg1—Cl2i	94.45 (7)	N1B—C3B—H3B	119.4
Cl4—Hg2—Cl5	141.70 (10)	C2B—C3B—H3B	119.4
Cl4—Hg2—Cl6	112.72 (10)	C4A—C5A—C1A	119.1 (10)
Cl5—Hg2—Cl6	105.06 (9)	C4A—C5A—H5A	120.5
Cl4—Hg2—Cl6ii	95.28 (8)	C1A—C5A—H5A	120.5
Cl5—Hg2—Cl6ii	87.53 (8)	C5A—C4A—N1A	120.7 (9)
Cl6—Hg2—Cl6ii	94.73 (7)	C5A—C4A—H4A	119.6
Hg1—Cl2—Hg1i	85.55 (7)	N1A—C4A—H4A	119.6
Hg2—Cl6—Hg2ii	85.27 (7)	N1A—C3A—C2A	120.3 (9)
C4B—N1B—C3B	119.8 (9)	N1A—C3A—H3A	119.9
C4B—N1B—H1B	120.1	C2A—C3A—H3A	119.9
C3B—N1B—H1B	120.1	N2B—C7B—H7Q	109.5
C3A—N1A—C4A	121.2 (8)	N2B—C7B—H7P	109.5
C3A—N1A—H1A	119.4	H7Q—C7B—H7P	109.5
C4A—N1A—H1A	119.4	N2B—C7B—H7D	109.5
C1B—N2B—C6B	121.7 (9)	H7Q—C7B—H7D	109.5
C1B—N2B—C7B	120.2 (9)	H7P—C7B—H7D	109.5
C6B—N2B—C7B	118.1 (8)	N2B—C6B—H6Q	109.5
N2B—C1B—C2B	122.2 (9)	N2B—C6B—H6D	109.5
N2B—C1B—C5B	121.8 (9)	H6Q—C6B—H6D	109.5
C2B—C1B—C5B	116.1 (9)	N2B—C6B—H6P	109.5
C4B—C5B—C1B	118.6 (9)	H6Q—C6B—H6P	109.5
C4B—C5B—H5B	120.7	H6D—C6B—H6P	109.5
C1B—C5B—H5B	120.7	N2A—C7A—H7I	109.5
C1A—N2A—C7A	122.1 (9)	N2A—C7A—H7J	109.5
C1A—N2A—C6A	120.1 (9)	H7I—C7A—H7J	109.5
C7A—N2A—C6A	117.6 (9)	N2A—C7A—H7K	109.5
C3A—C2A—C1A	121.6 (9)	H7I—C7A—H7K	109.5
C3A—C2A—H2A	119.2	H7J—C7A—H7K	109.5
C1A—C2A—H2A	119.2	N2A—C6A—H6K	109.5
N1B—C4B—C5B	123.3 (11)	N2A—C6A—H6I	109.5
N1B—C4B—H4B	118.4	H6K—C6A—H6I	109.5
C5B—C4B—H4B	118.4	N2A—C6A—H6J	109.5
N2A—C1A—C2A	122.8 (9)	H6K—C6A—H6J	109.5
N2A—C1A—C5A	120.0 (9)	H6I—C6A—H6J	109.5

D—H···A	D—H	H···A	D···A	D—H···A
N1A—H1A···Cl3	0.86	2.54	3.239 (8)	140
N1B—H1B···Cl5	0.86	2.46	3.195 (10)	145
C2B—H2B···Cl1iii	0.93	2.82	3.634 (11)	147
C3A—H3A···Cl5	0.93	2.75	3.485 (11)	136