A Review of Perovskite Photovoltaic Materials' Synthesis and Applications via Chemical Vapor Deposition Method.

Perovskite photovoltaic materials (PPMs) have emerged as one of superstar object for applications in photovoltaics due to their excellent properties-such as band-gap tunability, high carrier mobility, high optical gain, astrong nonlinear response-as well as simplicity of their integration with other types of optical and electronic structures. Meanwhile, PPMS and their constructed devices still present many challenges, such as stability, repeatability, and large area fabrication methods and so on. The key issue is: how can PPMs be prepared using an effective way which most of the readers care about. Chemical vapor deposition (CVD) technology with high efficiency, controllability, and repeatability has been regarded as a cost-effective road for fabricating high quality perovskites. This paper provides an overview of the recent progress in the synthesis and application of various PPMs via the CVD method. We mainly summarize the influence of different CVD technologies and important experimental parameters (temperature, pressure, growth environment, etc.) on the stabilization, structural design, and performance optimization of PPMS and devices. Furthermore, current challenges in the synthesis and application of PPMS using the CVD method are highlighted with suggested areas for future research.

1. Introduction

Perovskite is a kind of material with the same crystal structure as calcium titanate (CaTiO3), which was discovered by Gustav Rose in 1839 [1]. The perovskite material (PM) structure formula is generally ABX3, where A and B are two cations and X is anion, as shown in Figure 1 [2]. This unique crystal structure gives it many unique physical and chemical properties, such as broadband bandgap tunability, high carrier mobility, high optical gain, strong nonlinear response, and simplicity of their integration with other types of optical and electronic structures [3,4,5,6,7,8]. Due to its excellent physical and chemical properties, especially optical properties, perovskite materials are now widely applied for constructing photovoltaic solar cells (PSCs) [2,9,10,11].

Figure 1

Crystal structure of the perovskite ABX3 form.

Up to now, great progress has been made in the preparation and application of bulk PPMs. The perovskite family now includes hundreds of substances, ranging from organic materials, inorganic materials to organic–inorganic materials, from polycrystalline film to bulk single crystal [12]. However, introduction of many defects and grain boundaries in three-dimensional (3D) bulk PPMS is unavoidable [13], which inevitably degrade its optoelectronic properties. Recently, low-dimensional PPMS with high quality have begun to receive increasing attention, primarily for their tunable optical and electronic properties due to quantum-size effects as well as their enhanced photoelectric performance compared with bulk materials. Moreover, perovskites are considered to be a class of important low-dimensional layered materials, whose optical properties can be controlled by varying the number of layers, particularly at thicknesses lower than their exciton Bohr radius. Therefore, the shape-, size-, and thickness-controlled synthesis of low-dimensional PPMs has recently been a hot topic of research. Various low-dimensional morphologies, including zero-dimensional (0D) morphologies, such as quantum dots and nanoparticles; one-dimensional (1D) morphologies, such as nanowires and nanorods; and two-dimensional (2D) morphologies, such as nanoplates and nanosheets, have been prepared and applied [14,15,16,17,18,19,20,21].

Due to potential applications of perovskite materials (PMs) in photovoltaics wide spread interest has focused on exploring various synthesis methods to obtain high quality perovskite materials for constructing designed devices with improved performance. Up to now, many synthesis methods—such as solution process [4,22,23,24,25,26], thermal evaporation process [27], flash evaporation [28], doctor-blade coating method [29], slot-die coating method [30], spray deposition [31], ink-jet printing method [32], vapor-assisted solution process (VASP) [33], and so on—have been developed for preparing PPMs with well-designed dimensions for exploring factors which plays key role in dominating their properties. Among various approaches, the most studied solution method not only achieves highly efficient perovskite solar cells (PSCs) but also has a cost advantage. However, the uncontrolled rapid liquid reaction often generates rough, porous, and less-stable perovskite films with incomplete conversions, resulting in large variations on film morphology and Photovoltaic (PV) response [24,25,26]. Inversely, thermal evaporation can generate high-quality perovskite films with smooth and pinhole-free morphologies. However, there are a few of disadvantages in thermal evaporation process, such as low material utilization, and high equipment investment and energy consumption, hampering its further application [27,28]. The rest technologies often produce poor perovskite film quality, and are also difficult to scale up [29,30,31,32]. VASP methods require manipulations protecting atmosphere, and show poor controllability and versatility, unsuitable for their mass production [33]. Therefore, development of a new class of advanced fabrication technology shall be critical for the future commercialization of PPMs.

Soon after, as an evolution of VASP, an array of CVD techniques [2,34,35,36,37,38,39]—such as one-step and two-step tubular CVD, in situ tubular CVD (ITCVD), aerosol-assisted CVD (AACVD), hybrid physical-chemical vapor deposition (HPCVD), plasma-enhanced CVD (PECVD), and so on—were developed to grow high-quality PPMs. At present, CVD of perovskites is a promising alternative to solution based methods of fabrication due to the relative ease of patterning, the ability to batch process, the wide range of material compatibility, and the potential for uniform large-area deposition.

Here, in this review paper, CVD method—as one of the key technologies for preparing many kinds of advanced semiconductor materials with excellent properties—is mainly mentioned for preparing PPMs to construct optimal devices. For details, in this topical review, we present the recent developments of synthesis and application of various PPMs via the CVD method. We begin with the characteristics, classification, reaction process, and application of CVD method. In the following section, we mainly summarize the influence of different CVD technologies and important experimental parameters (temperature, pressure, growth environment, etc.) on the PPMs and devices. In particular, we aim to show why CVD technology can improve the stability of materials and devices, and can help material and device design, thus improving material and device performance. Finally, current challenges in the synthesis and application of PPMs using the CVD method are highlighted with suggested areas for future research.

2. CVD Method

CVD is a process for producing solid products from gases, and is a mature, lost cost, high efficiently technology for fabricating various kinds of semiconductor materials. CVD equipment mainly includes gas source control unit, deposition reaction chamber, deposition temperature control unit and vacuum exhaust and pressure control unit, and some experimental devices also have enhanced excitation energy control components. Therefore, according to the heating mode classification, it can be divided into thermal activation (resistance, high-frequency induction or infrared radiation heating, etc.), plasma enhancement, laser enhancement, microwave plasma enhancement, and other deposition modes, as shown in Table 1. In accordance with the reaction pressure classification, CVD can be divided into atmospheric pressure CVD (APCVD), low-pressure CVD (LPCVD) and ultrahigh vacuum CVD (UHVCVD, <10−6 Pa). According to gas phase classification, CVD can be further divided into Metal organic chemical vapor deposition (MOCVD), AACVD, direct liquid injection CVD (DLICVD), and HPCVD [40,41,42,43,44,45].

Table 1

Different CVD devices, heating mode and basic schematic diagram 1.

Device Form	Heating Method (Temperature Range, °C)	Principle Diagram
Tubular furnace type	Resistance heating mode (~1000)
Vertical type	Plate heating mode (~500)Induction heating mode (~1200)
Cylinder type	Induction heating mode (~1200)Infrared radiationheating mode (~1200)
Tandem surround type	Plate heating mode (~500)Infrared radiationheating mode (~1200)

1 Referrence [45].

Generally speaking, the reaction process of CVD mainly includes these parts: vapor-based reagents generation process, reactant transport process, chemical reaction process and reaction by-product removal process, as shown in Figure 2. Controllable variables of CVD method include gas flow rate and composition, deposition temperature, pressure, vacuum chamber shape, deposition time, and substrate material. In particular, basis of the relation between the gas diffusion constant, growth temperature, and gas pressure, the gas diffusion rate can be effectively tuned by an optimal combination of temperature and pressure. As such, CVD has the advantages of precise composition control, complete crystal deposition of thin films, large size and multi-substrate deposition, and deposition on complex substrates [40,41,42,43,44,45].

Figure 2

Basic reaction diagram of chemical vapor deposition.

3. Synthesis and Application of PPMs Using the CVD Methods

In the past 10 years, the perovskite photovoltaic film and low dimensional materials and their constructed devices have become a hot topic. Great progress has been made in the preparation and optimization of materials and devices. However, there are still having many problems (such as poor stability, poor repeatability, toxicity, and so on) and challenges to solve. In this part, we aim to clarify why CVD technology can improve the properties of perovskite photovoltaic thin film materials, especially the stability and structure design of the materials, so as to optimize the performance of related devices.

3.1. Perovskite Photovoltaic Film Synthesis through a Variety of CVD Technologies

3.1.1. Atmospheric Pressure and Low Pressure CVD (APCVD and LPCVD) Method

APCVD is a promising approach for producing high quality and large area film materials. In the last few years, one or two step APCVD methods have been used to fabricate perovskite films [46,47,48,49,50,51,52]. In 2015, one-step CVD method was used to fabricate planar heterojunction PSCs. By systematically optimizing the CVD parameters, such as temperature and growth time, high quality perovskite films of CH3NH3PbI3 and CH3NH3PbI3−xClx were obtained. The solar power conversion efficiency (PCE) can be up to 11.1% [46]. At the same year, a two-step sequential tubular CVD (STCVD) method was first employed to fabricate MAPbI3 (MA=CH3NH3) material under open-air conditions and PSCs [47]. The measurement results showed that the device performance via STCVD method is significantly enhanced comparing with that of by the other methods of synthesis. For instance, the device Voc can be boost from 0.915 V to 1.001 V, with an impressive enhancement of 86 mV. The best PCE is greatly improved from 10.29% to 13.76%. That is to say, the STCVD method shows high potential to be applied in the commercial production of PSCs, due to the characteristics of high efficiency, stable feature, and low cost. Since then, atmospheric CVD technology has been used to prepare various perovskite films, such as CsFAPbI3, CsFAPbIBr, HC(NH2)2PbI3xClx, and so on [48,49,50,51,52]. These reported works prove that APCVD is a promising technique because it uses a scalable vapor based growth process and the resultant modules maintain a high steady state power at larger areas when compared to modules grown by a reference solution process [22,23,24].

LPCVD are important thin film deposition techniques based on adsorption and subsequent surface reactions of precursor molecules in a high vacuum environment [53]. The schematic diagram of LPCVD instrument is shown in Figure 3. LPCVD is first introduced into fabrication of MAPbI3 perovskites by Luo group in 2015 [34]. Experimental results show that the prepared MAPbI3 films under low pressure have good crystallization, strong absorption, high stability, and long carrier diffusion length. Uniform and well-defined MAPbI3 layers are observed to be fully covered on the substrates, with a roughness of 19.6 nm and grain size up to 500 nm. Next year, Chen et al. have developed a different one-zone LPCVD to fabricate perovskites [54]. In this work, MAI and PbI2 are both loaded on a capped graphite boat, and then reacted at 120 °C for 60 or 120 min under a pressure of 133.3 Pa In this way, efficient PSCs of perovskite modules with a PCE of 6.22% on an active area of 8.4 cm2 are obtained. In addition, the crucial dependence of working pressure on the film formation is also revealed. Then, Qi group synthesize the FAPbI3 using the CVD with a pressure of ~100 Pa and a flow of drying nitrogen [55,56]. Cui group demonstrated an organic cation exchange concept for the preparation of high-quality a-FAPbI3 films using the CVD method under 10−2 Pa [57]. The PCE of the device was 12.4% based on the mesoscopic structure with no hysteresis. Since then, various PMs such as CH3NH3PbI3, (CH3NH3)3Bi2I9, and CsPbBr3 have been successfully prepared in low-pressure or ultra-low-pressure CVD systems [58,59,60,61,62,63,64,65,66,67]. The published works in recent years using the LPCVD method to fabricated perovskite materials are summarized and listed in Table 2.

Figure 3

Schematic diagram of LPCVD instrument. Reproduced with permission from reference [34].

Table 2

Perovskite materials were synthesized by LPCVD technique.

Perovskite Material	Pressure	PCE (%)	Ref.
CH3NH3PbI3	1 Torr	14.99 (Mesoscopic)	[54]
		15.37 (Planar)
FAI (Formamidinium iodide)	2 × 10−2 Pa	14.2	[55]
CH3NH3PbI3	1 × 10−3 Pa	15.6	[56]
α-FAPbI3	10−2 Pa	12.4	[57]
AMX3	10−5–10−6 mbar	~	[58]
CH3NH3PbBrI3-x	170 Torr	~	[59]
CH3NH3I(MAI)	~	16.42	[60]
CH3NH3PbI3	10 hPa	~	[61]
CsPbX3 (X = Cl, Br, I)	4.8(4.8,5.2) Torr	5.9 (10.0, 8.3)	[62]
(CH3NH3)3Bi2I9	10−6 hPa	0.047	[63]
CH3NH3PbI3	104 Pa	~	[64]
CH3NH3PbI3	1 Torr	7.9	[65]
CsPbBr3	150 Pa	~	[66]
(CH3NH3)3Bi2I9	10 hpa	0.047	[67]

3.1.2. Aerosol Assisted CVD (AACVD) Method

Compared with other deposition methods, AACVD is a low-cost and scalable technique. AACVD process occurs under ambient pressure and requires moderately volatile precursors, which should be a very attractive film fabrication technology and has a good potential for scale-up. Lewis et al. first use the AACVD method to the fabrication of MAPbBr3 perovskite film in 2014 [68]. The dilute nebulized precursors are transported by N2 gas into the tubular reaction furnace. The yellow perovskite film is deposited at 250 °C. Subsequently, phase pure, compositionally uniform MAPbI3 films on large glass substrate are prepared by Palgrave in 2015 using the AACVD method [69]. Then, several research groups have developed a one-step AACVD method to deposit perovskite thin films [70,71]. For instance, Liu et al. present a novel NH4Cl + CH3NH3I mixing vapor-assisted CVD method to realize the low-temperature and rapid preparation of perovskite layers [71].

Next year, Binions et al. develop a two-step sequential AACVD method to deposit MAPbI3 film [72]. To obtain uniform and thick enough perovskite film, a modified three-step AACVD method was proposed by Afzal et al. [73]. In the three-step AACVD deposition technique, a cold-walled horizontal-bed AACVD reactor was used to deposit perovskite MAPbI3 film. To overcome the solubility limitation of bromide in conventional polar solvent, a novel Br2-vapor-assisted CVD method was elaborately design to realize the fast anion-exchange from CsPbI3 to CsPbBr3, and thus structural stability of inorganic perovskites is enhanced accordingly [74]. PSCs based on these perovskite materials demonstrate good long term stability and give ~90% of initial efficiencies even after 21 days of exposure to air.

3.1.3. Hybrid Physical CVD (HPCVD) Method

In 2014, Qi et al. first introduced HPCVD technology for the effective deposition of a perovskite layer [40]. In this method, PbX2 was evaporated in a high-vacuum environment to obtain uniform films, and methyl ammonium iodide (MAI) was then heated to 185 °C and transported into the reaction site by N2 gas to fabricate perovskite solar cells. Next year, high-quality CH3NH3PbI3 films and corresponding solar cells were prepared by HPCVD method with a reaction temperature of 100 °C [75]. By optimizing the reaction temperature and pressure, efficient CH3NH3PbI3 solar cells were fabricated with high conversion efficiency up to 12.3%. In the same year, Peng etc. [76] also synthesized the high-quality CH3NH3PbI3 films using the HPCVD process in a vacuum and isothermal environment. CH3NH3PbI3 solar cells with high PCE up to 14.7% were fabricated at 82 °C. In 2016, all-vacuum processed methyl ammonium lead halide perovskite by a sequence of physical vapor deposition of PbI2 and CVD of CH3NH3I under a static atmosphere was fabricated [77,78]. A dependence of residual PbI2 on the solar cells performance is displayed, while photovoltaic devices with efficiency up to 11.6% were achieved. It should be pointed out that, the diffusion rate can be varied over a wide range by controlling its gas pressure when the growth temperature is limited to reasonable value for the HPCVD system. Thus, high-quality perovskite films with fully covered, smooth surfaces are achieved by using the HPCVD method [37,79]. A hybrid CVD with cation exchange method is developed for preparation of Cs-substituted mixed cation perovskite films [80,81,82]. This technique shows a high potential toward scaling-up the Cs-substituted perovskite from lab solar cell scale 1.5 cm2 to module scale 5 cm2 with a high module PCE of 14.6% (12.0 cm2 active areas). Cs0.07FA0.93PbI3 PSC prepared by this method shows 14.0% PCE after 1200 min steady-state measurement, demonstrating the promising device stability achieved by this perovskite fabrication technique [83].

3.2. Low Dimensional Perovskite Photovoltaic Materials Synthesized by CVD Technologies

Over the last five years, there has been tremendous progress in the development of nanoscale PPMs which possess a wide range of band gaps and tunable optical and electronic properties. These excellent photoelectric properties and ultra-high density of nanostructured PPMs can serve as ideal candidates for [81,82,83,84,85,86,87,88,89] solar cells.

The emerging 2D PPMs are attracting more interest due to the long charge carrier lifetime, high photoluminescence quantum efficiency, and great defect tolerance [90]. Recently, Ha et al. first developed CVD synthesis of perovskite nanoplatelets on mica substrate [20]. This method was further employed by Su group [91] to push the ample thickness (below 10 nm) on mica substrates. The weak material–substrate interaction and low cohesive energy of the perovskite lead to the growth of large-scale ultrathin 2D crystals. Wang et al. [92] used a dual precursor CVD method to grown MAPbCl3 2D sheet with a thickness of 8.7 nm and lateral dimension of over 20 mm. Nanosheets with thicknesses as low as 1.3 nm have been synthesized using CVD at a low pressure of 40 Torr and 120 °C. Bao and other research teams [21,93,94,95] use the CVD to create 2D CH3NH3PbI3 perovskites. Lan et al. show that process pressure can be used to grow PbI2 with high crystallinity on roughened surfaces [96]. CVD was also used to convert the as-synthesized nanosheets to CH3NH3PbI3. Chen et al. synthesized ultrathin (BA)2(MA)n−1PbnBr3n+1 perovskites with thickness down to 4.2 nm and lateral dimension up to 57 mm [97]. These results suggest that the one-step and two-step vapor phase synthetic approaches are powerful in prepare low dimensional PMs.

Particularly, thin 2D materials can be used as hole extraction layers in organolead halide PSCs [98,99]. MoS2 and WS2 layers with a polycrystalline structure were synthesized by a thermal CVD system at 950 °C and 1 Torr pressure. The PCE of the MoS2- and WS2-based PSCs were 9.53% and 8.02%, respectively. These results suggest that 2D materials such as MoS2 and WS2 can be promising candidates for the formation of hole extraction layers in the PSCs. FAPb(BrxI1−x)3 nanoplatelets with gradient bandgap are fabricated using CVD method [100]. During the whole vapor conversion process, CVD furnace temperature was 140 °C, and pressure was about 500 mTorr with a controlled Ar gas flow rate of 35 sccm (standard cubic centimeters per minute) and reaction time 2 h.

4. Electrode, Window, Blocking and Electron Transport Layer Materials of Perovskite Devices Prepared by CVD Technologies

Interfacing perovskites with other 1D or 2D materials including graphene, carbon nanotubes (CNTs), SnO2, ZnO, CuOx, and CdS significantly broadens the application range of the perovskite materials. Therefore, using various CVD technologies to prepare high-quality electrode, window, blocking, and electron transport layer materials of perovskite devices can effectively promote device design and enhances the performance of the functional devices.

4.1. APCVD Method

CVD synthesized graphene films can be used as electrodes in normal structure PSCs to replace the traditional conductive fluorine-doped or indium tin oxide (FTO or ITO) electrodes, either on rigid substrates or on flexible substrates [101,102,103,104,105,106,107,108,109,110,111,112,113,114,115]. Luo et al. [101] prepared flexible PSCs with a PCE of 11.9% using the graphene as bottom electrode and CNTs as top electrode. Meng et al. [102] synthesized the high quality graphene using CVD method as bottom electrodes in normal structure PSC. An efficiency of 13.93% was obtained from the reverse scan of the current density–voltage (J–V) curves. In 2015, Sung et al. [103] first reported the adoption of graphene as bottom electrodes in inverted structure PSCs. In 2016, Liu et al. [104] also successfully fabricated the flexible PSCs with double layer graphene films as bottom electrodes. The reasonable transparency is ~90% in the visible range, which is much higher than that of ITO electrode [105,106]. The semitransparent PSC using the graphene as top electrode is shown in Figure 4. The following year, Yoon and his collaborators [107] reported super-flexible PSCs by using MoO3-modified single-layer CVD graphene as bottom electrodes with a maximum PCE of 16.8%. The graphene-based flexible PSCs can maintain over 90% of the original efficiencies after bending test of 1000 cycles at a bending radius of 2 mm. In order to attain higher efficiencies of the graphene-based PSCs, how to further reduce the sheet resistance of graphene films is a key problem. Im and his coworkers employed AuCl3-doped graphene [116,117,118] and amide TFSA-doped graphene [109] as bottom electrodes to make super-flexible PSCs. After highly p-type chemical doping with two dopants, the sheet resistance of single layer graphene film decreased significantly to approximately 100 Ω sq−1, which is much lower than the monolayer graphene. Lang et al. [110] implemented large-area CVD graphene films to obtain semitransparent PSCs and achieving a champion PCE of 13.2% in the final tandem cells. Zhou et al. [111] successfully fabricated terminal perovskite/Si tandem PSCs with a high efficiency of 18.1%. In addition, graphene can also be used as electron transport and blocking layer [112]. Single layer graphene was introduced into PSCs as an air and metal blocking layer to protect the perovskite layer, because the graphene is electrically conductive and can block the metal ions, oxygen, and water into the perovskite layer. Therefore, PSCs including a graphene layer showed a significantly enhanced stability under ambient conditions or thermal annealing process [113]. Therefore, we can see it clearly that the conductivity and quality of the transferred graphene films can severely impact the device performance of PSCs.

Figure 4

Schematic diagram of the semitransparent PSC using the graphene as top electrode. Reproduced with permission from reference [105].

Except the graphene, CNTS (network films) prepared by CVD method are also used as electrodes of perovskite devices [114,115]. CNT network films were synthesized using the floating catalyst CVD method using a tube furnace. The transparent CNTs top electrode acts as hole collecting layer and light transmission. The PSCs with a PCE up to 8.31% has been achieved. The published works of using the graphene and CNT materials as top and bottom electrodes are summarized and listed in Table 3.

Table 3

Summary of the PSCs with graphene and CNTs electrodes.

Electrode Material	Device Structures	PCE (%)	Ref.
Graphene CNTS	FET/Graphene/TiO2/PCBM/MAPbI3/Spiro-OMeTAD/CNTs	11.9	[101]
Graphene	Quartz/graphene/C60/MAPbI3/carbon	13.93	[102]
Graphene	Glass/graphene/MoO3/PEDOT:PSS/MAPbI3/C60/BCP/LiF/Al	17.1	[103]
Graphene	PET/ZEOCOAT/graphene/P3HT/MAPbI3/PC71BM/Ag	11.5	[104]
Graphene	FTO/TiO2/MAPbI3-xClx/Spiro-OMeTAD/PEDOT:PSS/graphene	12.37	[105]
Graphene	PET/graphene/PEDOT:PSS/MAPbI3/PCBM/Al	13.94	[106]
Graphene	PEN/graphene/MoO3/PEDOT:PSS/MAPbI3/C60/BCP/LiF/Al	16.8	[107]
Graphene	PET/graphene/PEDOT:PSS/FAPbI3−xBrx/PCBM/Al	17.9	[108]
Graphene	Glass or PDMS/graphene/PEDOT:PSS/FAPbI3−xBrx/PCBM/Al	18.3	[109]
Graphene	FTO/TiO2/MAPbI3/Spiro-OMeTAD/graphene	6.2	[110]
Graphene	FTO/TiO2/MAPbI3−xClx/Spiro-OMeTAD/PEDOT:PSS/graphene	11.8	[111]
CNTs	Tifoil/CH3NH3PbI3/TiO2NTs/Spiro-OMeTAD/CNTs	8.31	[114]
CNTs	Glass/FTO/TiO2/CH3NH3PbI3/CNTs	3.88	[115]

4.2. PECVD Method

Large area and functional TiO2−x films using as the hole blocking electron transport layers in PSC architectures are synthesized by roll to roll PECVD system [116]. The PECVD system has a dual laminar flow design to provide two reaction zones to improve net growth rate and uniformity and minimize the entrainment of surrounding air. Each reaction zone incorporates a dielectric barrier system to provide plasma activation and extraction of waste products to avoid contamination. The film thickness can be effectively controlled by the number of passes under the coating head. The experimental results showed that PECVD is capable for producing 50 nm TiO2−x layers with sufficient quality and uniformity for use in perovskite based photovoltaic devices and increasing cell efficiency further.

4.3. Pulsed CVD Method

Pulsed CVD was first used by Bush et al. to prepare SnO2/ZTO window layer of perovskite/silicon tandem solar cells devices [117]. The vapor processes can produce a compact, uniform, and highly transparent SnO2/ZTO bilayer with efficient hole-blocking ability and sputter buffer layer properties. The devices have a good thermal and ambient stability compared with the standard encapsulation such as glass. The perovskite cells were coupled with silicon heterojunction bottom cells and ITO layers. The resulting tandem reached an efficiency of 23.6% with no hysteresis. The maximum power can be stabilized over more than 30 minutes under illumination.

Then, in order to solve the problems of high thermal mismatch and low fracture level of PSCs and improve the conversion efficiency of the devices, Cheacharoen et al. prepared the 4 nm SnO2 and 2 nm Zinc oxide tin layer by pulsed CVD method at 100 °C [118]. The stabilities of the encapsulated PSCs were measured by the International Electrotechnical Commission (IEC) 61646 standard test of 200 temperature cycles from −40 °C to 85 °C and observed no visible delamination and less than a 10% change in performance.

4.4. Physical Chemical Vapor Deposition (PCVD) Method

CdS nanorods arrays and thin film as an electron transport layer in PSCs are fabricated by PCVD method [119,120]. A parametric optimization of the CdS layer thickness and an advantageous in situ Cd-doping of the perovskite thin film lead to a high PCE of ~14.68%. In particular, this lower synthesis temperature (<85 ℃) is convenient for implementation a flexible PSCs directly upon plastic PET substrate. Then, 3D architecture PSCs using the CdS nanorods arrays as an electron transport layer were designed and prepared via a layer-by-layer PCVD process. The CdS NRs not only provided a scaffold to the perovskite film, but also increased the interfacial contact between the perovskite film and electron transport layer. As an optimized result, a high PEC of 12.46% with a short-circuit current density of 19.88 mA/cm−2, an open-circuit voltage of 1.01 V was obtained.

4.5. AACVD Method

As mentioned earlier, CNT film has shown to be very effective in replacing metal electrodes and enhancing the stability of PSCs in air environment. Randomly oriented CNT networks with high purity and long nanotube bundle length are synthesized by the AACVD method [121]. Then the carbon-sandwiched perovskite device was studied by using the CVD synthesized CNT on top of MAPbI3. Characterization results show that the encapsulated device (with a structure ITO/C60/MAPbI3/CNT) shows high stability against both air and light, with around 90% of the initial efficiency after 2000 h under actual operation conditions.

As a variant of conventional CVD process, AACVD allows for the use of non-volatile metal precursors as the limiting factor is soluble substance rather than volatile substance. Furthermore, the AACVD growth rate could reduce to one comparable or lower than that of atomic layer deposition, making it attractive for ultra-thin film growth. In 2018, ultrathin and compact ZnO films have been successfully deposited on FTO electrodes via AACVD method [122]. ZnO films were carried out in a horizontal bed cold-walled tubular reactor with a size 170 × 60 mm. The deposition temperature was set at 350 °C and the reaction time was 8 mins. After deposition, samples were annealed in a tube furnace at 500 °C for 1 hour under argon atmosphere. Planar PSCs with conventional material CH3NH3PbI3 were fabricated under ambient conditions and best PCE of 11.75% was achieved. Also last year, ultra-thin CuOx coatings using as a hole extraction layer in inverted PSCs was prepared by AACVD technique [123]. The resulting CH3NH3PbI3 PSC achieves a maximum PCE of 8.26%, demonstrating the efficient hole transporting ability in the CuOx coatings.

5. Conclusions and Future Outlook

In summary, we have made a review on the preparation and application of perovskite photovoltaic and related device materials by a variety of CVD technologies—including APCVD, LPCVD, HPCVD, HCVD, AACVD, PECVD, and pulsed CVD—and the most recent progress was highlighted over the past five years. Perovskite photovoltaic materials and related device properties with different compositions, morphologies, structures, and dimensions are all discussed. Obviously, it is observed that high stability, high controllability, and high scalability PPMS and high performance devices could be achieved by CVD method through controlling gas flow rate, growth temperature, pressure, and reaction time of the reaction systems. For example, high efficient PSCs with a PCE 23.6% have been achieved by utilizing CVD method to prepare needed materials. Thus, CVD methods owning high stability, low-cost, and scalable features are one of the best choices to prepare high quality perovskite photovoltaic materials, which could be applied for potential industry applications of building PSCs with high efficiency.

However, just as impressive as the progress has been, there are novel opportunities and challenges remaining:

1. Systematic study of synthesis mechanism of CVD method

There is no doubt that great progress has been made in the preparation and optimization of PPMS and devices using various CVD technologies. However, scientists are mainly concerned about how to realize materials and devices with CVD method, and lack of attention and in-depth research on the physical mechanism of synthesis. Understanding the mechanism behind the formation of these perovskite photovoltaic materials will help researchers to come up with effective strategies to combat the emerging challenges of this family of materials, such as stability under ambient conditions and toxicity, towards next generation applications in photovoltaics and optoelectronics.

2. Stabilization

A major limiting factor for the commercialization of perovskite photovoltaic devices is the low stability of the materials. They react very easily with water in the air and are easily oxidized by oxygen in the air. At the same time, the thermal stability of the material is poor, easy to decompose when heated. The longest reported stabilization time is now in the hundreds of days. The stability problems will be amplified at the nanoscale due to the relative surface area being much larger compared to the bulk materials. Thus, stabilizing of the materials and devices is critically important for the perovskites. Selecting ideal encapsulation and protection materials for the perovskites during the process of fabrication is important.

3. Novel perovskite structures

As we mentioned in the introduction, the perovskite structure takes the form of ABX3. Within this framework, lead and tin are the most commonly used in B position, resulting in their physical properties being unable to be tuned to a precise extent. Searching for novel complex perovskite structures may solve the problem. In particular, many groups have demonstrated that the optical and electrical properties of perovskite photovoltaic materials greatly depend on their dimensions. Thus, ability to fully manipulate their dimensions will be vital for understanding the structure–property–device behavior relationship.

4. Interfaces and heterojunctions

Low-dimensional perovskite materials possess large and well-defined surfaces, and such surfaces can interact strongly with another material’s surface when bringing these two materials together to form a heterojunction. Perovskite photovoltaic materials interfacing with low-dimensional graphene, CNTs, SnO2, ZnO, CuOx, and CdS materials using the CVD method have been proved can significantly broadens the application and enhances the performance of the functional devices. However, directly growing a lateral heterojunction along the edge of the perovskite low-dimensional materials remains challenging. More complicated heterojunctions with better controlled structures, compositions, and performance are desired in the near future.

CVD technology has shown some advantages and potential applications in preparing perovskite photovoltaic materials and devices than other synthetic methods. It could benefit from the controllable and optimizable growth temperature, pressure, and the moderate gas-phase reaction rate in CVD process. Therefore, the continued development of cost-effective CVD technology is crucial to further commercialization of perovskite photovoltaic devices. This method must draw deep attention from a wide range of researchers and we also hope that it could be vigorously promoted in perovskite materials and devices.