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Literature DB >> 31485379

Enantioselective Synthesis of Nonracemic Geminal Silylboronates by Pt-Catalyzed Hydrosilylation.

Adam A Szymaniak, Chenlong Zhang, John R Coombs, James P Morken.

Abstract

A Pt-catalyzed enantioselective hydrosilylation of alkenylboronates is described. This reaction occurs with high regio- and enantioselectivity, providing a convenient route to chiral non-racemic geminal silylboronates. These compounds are useful reagents in stereoselective synthesis.

Entities: Chemical Disease Gene

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Year: 2018 PMID： 31485379 PMCID： PMC6726405 DOI： 10.1021/acscatal.8b00221

Source DB: PubMed Journal: ACS Catal Impact factor: 13.084

30 in total

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