Literature DB >> 23002712

Direct stereospecific amination of alkyl and aryl pinacol boronates.

Scott N Mlynarski1, Alexander S Karns, James P Morken.   

Abstract

The direct amination of alkyl and aryl pinacol boronates is accomplished with lithiated methoxyamine. This reaction directly provides aliphatic and aromatic amines, stereospecifically, and without preactivation of the boronate substrate.

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Year:  2012        PMID： 23002712      PMCID： PMC3481838          DOI： 10.1021/ja305448w

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  14 in total

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3.  Copper-catalyzed amination of arylboronates with N,N-dialkylhydroxylamines.

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6.  Catalytic asymmetric hydroboration/amination and alkylamination with rhodium complexes of 1,1'-(2-diarylphosphino-1-naphthyl)isoquinoline

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Review 10.  Homologation and alkylation of boronic esters and boranes by 1,2-metallate rearrangement of boronate complexes.

Authors:  Stephen P Thomas; Rosalind M French; Vishal Jheengut; Varinder K Aggarwal
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6.  Copper-Catalyzed Amidation of Primary and Secondary Alkyl Boronic Esters.

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7.  Nickel-Catalyzed Enantioconvergent Borylation of Racemic Secondary Benzylic Electrophiles.

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8.  Metal-Free Direct Amidation of Naphthoquinones Using Hydroxamic Acids as an Amide Source: Application in the Synthesis of an HDAC6 Inhibitor.

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9.  A general, modular method for the catalytic asymmetric synthesis of alkylboronate esters.

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10.  Selective formation of secondary amides via the copper-catalyzed cross-coupling of alkylboronic acids with primary amides.

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