Metal-Organic Frameworks in Polymer Science: Polymerization Catalysis, Polymerization Environment, and Hybrid Materials.

The development of metal-organic frameworks (MOFs) has had a significant impact on various fields of chemistry and materials science. Naturally, polymer science also exploited this novel type of material for various purposes, which is due to the defined porosity, high surface area, and catalytic activity of MOFs. The present review covers various topics of MOF/polymer research beginning with MOF-based polymerization catalysis. Furthermore, polymerization inside MOF pores as well as polymerization of MOF ligands is described, which have a significant effect on polymer structures. Finally, MOF/polymer hybrid and composite materials are highlighted, encompassing a range of material classes, like bulk materials, membranes, and dispersed materials. In the course of the review, various applications of MOF/polymer combinations are discussed (e.g., adsorption, gas separation, drug delivery, catalysis, organic electronics, and stimuli-responsive materials). Finally, past research is concluded and an outlook toward future development is provided.