Literature DB >> 31356382

Tumor Contrast Enhancement and Whole-Body Elimination of the Manganese-Based Magnetic Resonance Imaging Contrast Agent Mn-PyC3A.

Derek J Erstad1, Ian A Ramsay2, Veronica Clavijo Jordan2,3, Mozhdeh Sojoodi1, Bryan C Fuchs1, Kenneth K Tanabe1, Peter Caravan2,3, Eric M Gale2.   

Abstract

OBJECTIVES: The goals of this study were to compare the efficacy of the new manganese-based magnetic resonance imaging (MRI) contrast agent Mn-PyC3A to the commercial gadolinium-based agents Gd-DOTA and to Gd-EOB-DTPA to detect tumors in murine models of breast cancer and metastatic liver disease, respectively, and to quantify the fractional excretion and elimination of Mn-PyC3A in rats.
METHODS: T1-weighted contrast-enhanced MRI with 0.1 mmol/kg Mn-PyC3A was compared with 0.1 mmol/kg Gd-DOTA in a breast cancer mouse model (n = 8) and to 0.025 mmol/kg Gd-EOB-DTPA in a liver metastasis mouse model (n = 6). The fractional excretion, 1-day biodistribution, and 7-day biodistribution in rats after injection of 2.0 mmol/kg [Mn]Mn-PyC3A or Gd-DOTA were quantified by Mn gamma counting or Gd elemental analysis. Imaging data were compared with a paired t test; biodistribution data were compared with an unpaired t test.
RESULTS: The postinjection-preinjection increases in tumor-to-muscle contrast-to-noise ratio (ΔCNR) 3 minutes after injection of Mn-PyC3A and Gd-DOTA (mean ± standard deviation) were 17 ± 3.8 and 20 ± 4.4, respectively (P = 0.34). Liver-to-tumor ΔCNR values at 8 minutes postinjection of Mn-PyC3A and Gd-EOB-DTPA were 28 ± 9.0 and 48 ± 23, respectively (P = 0.11). Mn-PyC3A is eliminated with 85% into the urine and 15% into the feces after administration to rats. The percentage of the injected doses (%ID) of Mn and Gd recovered in tissues after 1 day were 0.32 ± 0.12 and 0.57 ± 0.12, respectively (P = 0.0030), and after 7 days were 0.058 ± 0.051 and 0.19 ± 0.052, respectively (P < 0.0001).
CONCLUSIONS: Mn-PyC3A provides comparable tumor contrast enhancement to Gd-DOTA in a mouse breast cancer model and is more completely eliminated than Gd-DOTA; partial hepatobiliary elimination of Mn-PyC3A enables conspicuous delayed phase visualization of liver metastases.

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Year:  2019        PMID: 31356382      PMCID: PMC6785385          DOI: 10.1097/RLI.0000000000000593

Source DB:  PubMed          Journal:  Invest Radiol        ISSN: 0020-9996            Impact factor:   6.016


  31 in total

Review 1.  The biological fate of gadolinium-based MRI contrast agents: a call to action for bioinorganic chemists.

Authors:  Mariane Le Fur; Peter Caravan
Journal:  Metallomics       Date:  2019-02-20       Impact factor: 4.526

2.  Gadolinium--a specific trigger for the development of nephrogenic fibrosing dermopathy and nephrogenic systemic fibrosis?

Authors:  Thomas Grobner
Journal:  Nephrol Dial Transplant       Date:  2006-01-23       Impact factor: 5.992

3.  Intracranial Gadolinium Deposition Following Gadodiamide-Enhanced Magnetic Resonance Imaging in Pediatric Patients: A Case-Control Study.

Authors:  Jennifer S McDonald; Robert J McDonald; Mark E Jentoft; Michael A Paolini; David L Murray; David F Kallmes; Laurence J Eckel
Journal:  JAMA Pediatr       Date:  2017-07-01       Impact factor: 16.193

4.  Intensive Surveillance with Biannual Dynamic Contrast-Enhanced Magnetic Resonance Imaging Downstages Breast Cancer in BRCA1 Mutation Carriers.

Authors:  Rodrigo Santa Cruz Guindalini; Yonglan Zheng; Hiroyuki Abe; Kristen Whitaker; Toshio F Yoshimatsu; Tom Walsh; David Schacht; Kirti Kulkarni; Deepa Sheth; Marion S Verp; Angela R Bradbury; Jane Churpek; Elias Obeid; Jeffrey Mueller; Galina Khramtsova; Fang Liu; Akila Raoul; Hongyuan Cao; Iris L Romero; Susan Hong; Robert Livingston; Nora Jaskowiak; Xiaoming Wang; Marcio Debiasi; Colin C Pritchard; Mary-Claire King; Gregory Karczmar; Gillian M Newstead; Dezheng Huo; Olufunmilayo I Olopade
Journal:  Clin Cancer Res       Date:  2018-08-28       Impact factor: 12.531

5.  Double-dose gadoxetic Acid-enhanced magnetic resonance imaging in patients with chronic liver disease.

Authors:  Utaroh Motosugi; Tomoaki Ichikawa; Katsuhiro Sano; Hironobu Sou; Kojiro Onohara; Ali Muhi; Takatoshi Kitamura; Fumitake Amemiya; Nobuyuki Enomoto; Masanori Matsuda; Masami Asakawa; Hideki Fujii; Tsutomu Araki
Journal:  Invest Radiol       Date:  2011-02       Impact factor: 6.016

Review 6.  Chemistry of MRI Contrast Agents: Current Challenges and New Frontiers.

Authors:  Jessica Wahsner; Eric M Gale; Aurora Rodríguez-Rodríguez; Peter Caravan
Journal:  Chem Rev       Date:  2018-10-16       Impact factor: 60.622

7.  A Manganese-based Alternative to Gadolinium: Contrast-enhanced MR Angiography, Excretion, Pharmacokinetics, and Metabolism.

Authors:  Eric M Gale; Hsiao-Ying Wey; Ian Ramsay; Yi-Fen Yen; David E Sosnovik; Peter Caravan
Journal:  Radiology       Date:  2017-11-08       Impact factor: 11.105

8.  Dynamic contrast-enhanced perfusion MR imaging measurements of endothelial permeability: differentiation between atypical and typical meningiomas.

Authors:  Stanley Yang; Meng Law; David Zagzag; Hope H Wu; Soonmee Cha; John G Golfinos; Edmond A Knopp; Glyn Johnson
Journal:  AJNR Am J Neuroradiol       Date:  2003-09       Impact factor: 3.825

9.  High signal intensity in the dentate nucleus and globus pallidus on unenhanced T1-weighted MR images: relationship with increasing cumulative dose of a gadolinium-based contrast material.

Authors:  Tomonori Kanda; Kazunari Ishii; Hiroki Kawaguchi; Kazuhiro Kitajima; Daisuke Takenaka
Journal:  Radiology       Date:  2013-12-07       Impact factor: 11.105

10.  A Manganese Alternative to Gadolinium for MRI Contrast.

Authors:  Eric M Gale; Iliyana P Atanasova; Francesco Blasi; Ilknur Ay; Peter Caravan
Journal:  J Am Chem Soc       Date:  2015-12-04       Impact factor: 15.419

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  5 in total

1.  Manganese(II)-Based Responsive Contrast Agent Detects Glucose-Stimulated Zinc Secretion from the Mouse Pancreas and Prostate by MRI.

Authors:  Sara Chirayil; Veronica Clavijo Jordan; André F Martins; Namini Paranawithana; S James Ratnakar; A Dean Sherry
Journal:  Inorg Chem       Date:  2021-01-28       Impact factor: 5.165

2.  Positron Emission Tomography-Magnetic Resonance Imaging Pharmacokinetics, In Vivo Biodistribution, and Whole-Body Elimination of Mn-PyC3A.

Authors:  Iris Yuwen Zhou; Ian A Ramsay; Ilknur Ay; Pamela Pantazopoulos; Nicholas J Rotile; Alison Wong; Peter Caravan; Eric M Gale
Journal:  Invest Radiol       Date:  2021-04-01       Impact factor: 10.065

3.  L-EGCG-Mn nanoparticles as a pH-sensitive MRI contrast agent.

Authors:  Jiali Li; Xue Jiang; Lihuan Shang; Zhen Li; Conglian Yang; Yan Luo; Daoyu Hu; Yaqi Shen; Zhiping Zhang
Journal:  Drug Deliv       Date:  2021-12       Impact factor: 6.419

4.  Carbonized paramagnetic complexes of Mn (II) as contrast agents for precise magnetic resonance imaging of sub-millimeter-sized orthotopic tumors.

Authors:  Ruixue Qin; Shi Li; Yuwei Qiu; Yushuo Feng; Yaqing Liu; Dandan Ding; Lihua Xu; Xiaoqian Ma; Wenjing Sun; Hongmin Chen
Journal:  Nat Commun       Date:  2022-04-11       Impact factor: 17.694

5.  Thermodynamic Stability of Mn(II) Complexes with Aminocarboxylate Ligands Analyzed Using Structural Descriptors.

Authors:  Rocío Uzal-Varela; Francisco Pérez-Fernández; Laura Valencia; Aurora Rodríguez-Rodríguez; Carlos Platas-Iglesias; Peter Caravan; David Esteban-Gómez
Journal:  Inorg Chem       Date:  2022-08-22       Impact factor: 5.436

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