Literature DB >> 30916099

Mössbauer and mass spectrometry support for iron(ii) catalysts in enantioselective C-H activation.

Joachim Loup1, Tobias Parchomyk, Stefan Lülf, Serhiy Demeshko, Franc Meyer, Konrad Koszinowski, Lutz Ackermann.   

Abstract

A combination of electrospray-ionization mass spectrometry and Mössbauer spectroscopy was used to investigate the species generated in situ in highly enantioselective Fe/NHC-catalyzed C-H alkylations. The findings indicate an organometallic iron(ii)-NHC species to be of key relevance in the asymmetric catalysis.

Entities:  

Year:  2019        PMID： 30916099     DOI： 10.1039/c9dt00705a

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  4 in total

Review 1.  N-Heterocyclic Carbene Complexes in C-H Activation Reactions.

Authors:  Qun Zhao; Guangrong Meng; Steven P Nolan; Michal Szostak
Journal:  Chem Rev       Date:  2020-01-22       Impact factor: 60.622

Review 2.  Iron-Catalyzed C-H Functionalizations under Triazole-Assistance.

Authors:  Matteo Lanzi; Gianpiero Cera
Journal:  Molecules       Date:  2020-04-15       Impact factor: 4.411

3.  Identification of a Two-Coordinate Iron(I)-Oxalate Complex.

Authors:  Martin Mayer; Nina Vankova; Ferdinand Stolz; Bernd Abel; Thomas Heine; Knut R Asmis
Journal:  Angew Chem Int Ed Engl       Date:  2022-02-24       Impact factor: 16.823

4.  Iron-Electrocatalyzed C-H Arylations: Mechanistic Insights into Oxidation-Induced Reductive Elimination for Ferraelectrocatalysis.

Authors:  Cuiju Zhu; Maximilian Stangier; João C A Oliveira; Leonardo Massignan; Lutz Ackermann
Journal:  Chemistry       Date:  2019-12-09       Impact factor: 5.236
  4 in total

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