Co-pyrolysis of metal contaminated oily waste for oil recovery and heavy metal immobilization.

The treatment of metal-contaminated oily waste was investigated by using an approach of co-pyrolysis with hog fuel in a fixed bed reactor. Both oil recovery and heavy metal immobilization were evaluated. Three experimental factors, including pyrolysis temperature, reaction time, and hog fuel addition in the feedstock, were examined to find their effects on the treatment performance. Metal immobilization in the solid char obtained from co-pyrolysis was examined from its speciation characteristics. A higher pyrolysis temperature led to a decreased oil recovery but more non-bioavailable metal species in the char residue. This is also evident from the calculated risk index (RI) for eco-toxicity assessment, with RI of 34.6 and 117.1 at 600 °C and 400 °C, respectively. The addition of hog fuel into oily waste for co-pyrolysis also led to increased metal immobilization but a decreased overall oil recovery. A low temperature co-pyrolysis (400 °C) by adding 20% of hog fuel was found as the most effective oily waste disposal strategy with satisfactory oil recovery and an acceptable risk index of 54.1.