Literature DB >> 30620177

Palladium-Based Metal-Ligand Assemblies: The Contrasting Behavior upon Addition of Pyridine or Acid.

Suzanne M Jansze1, Kay Severin1.   

Abstract

The stability of five different [Pd n(N-donor) m]2 n+ assemblies was examined by performing disassembly experiments with pyridine and with trifluoroacetic acid. Pyridine-induced disassembly was found to be most pronounced for Pd complexes containing N-donor ligands of low basicity. At the same time, these assemblies displayed high acid resistance. The contrasting stability in the presence of acid or pyridine can be used for the pH-controlled switching between different metallosupramolecular structures.

Entities:  

Year:  2019        PMID： 30620177     DOI： 10.1021/jacs.8b12738

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  7 in total

Review 1.  Transformation networks of metal-organic cages controlled by chemical stimuli.

Authors:  Elie Benchimol; Bao-Nguyen T Nguyen; Tanya K Ronson; Jonathan R Nitschke
Journal:  Chem Soc Rev       Date:  2022-06-20       Impact factor: 60.615

2.  Donor Strengths Determination of Pnictogen and Chalcogen Ligands by the Huynh Electronic Parameter and Its Correlation to Sigma Hammett Constants.

Authors:  Qiaoqiao Teng; Ping Siang Ng; Jia Nuo Leung; Han Vinh Huynh
Journal:  Chemistry       Date:  2019-09-30       Impact factor: 5.236

3.  Multi-stimuli Control over Assembly and Guest Binding in Metallo-supramolecular Hosts Based on Dithienylethene Photoswitches.

Authors:  Ru-Jin Li; Jacopo Tessarolo; Haeri Lee; Guido H Clever
Journal:  J Am Chem Soc       Date:  2021-03-05       Impact factor: 15.419

4.  Light-Powered Dissipative Assembly of Diazocine Coordination Cages.

Authors:  Haeri Lee; Jacopo Tessarolo; Daniel Langbehn; Ananya Baksi; Rainer Herges; Guido H Clever
Journal:  J Am Chem Soc       Date:  2022-01-26       Impact factor: 15.419

5.  Entropy directs the self-assembly of supramolecular palladium coordination macrocycles and cages.

Authors:  D A Poole Iii; E O Bobylev; S Mathew; J N H Reek
Journal:  Chem Sci       Date:  2022-08-10       Impact factor: 9.969

6.  Dramatic Effect of A Ring Size of Alicyclic α-Dioximate Ligand Synthons on Kinetics of the Template Synthesis and of the Acidic Decomposition of the Methylboron-Capped Iron(II) Clathrochelates.

Authors:  Alexander L Pomadchik; Alexander S Belov; Ekaterina G Lebed; Irina G Belaya; Anna V Vologzhanina; Yan Z Voloshin
Journal:  Molecules       Date:  2021-06-30       Impact factor: 4.411

7.  Tunable Fullerene Affinity of Cages, Bowls and Rings Assembled by PdII Coordination Sphere Engineering.

Authors:  Bin Chen; Shinnosuke Horiuchi; Julian J Holstein; Jacopo Tessarolo; Guido H Clever
Journal:  Chemistry       Date:  2019-10-24       Impact factor: 5.236
  7 in total

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