| Literature DB >> 30561885 |
Leo Iu1, José A Fuentes1, Mesfin E Janka2, Kevin J Fontenot2, Matthew L Clarke1.
Abstract
The hydroformylation of propene to give predominantly iso-butanal has been achieved; class-leading selectivity is possible even at higher temperatures that deliver fast conversion. Racemic rhodium complexes of bidentate phospholane phosphites derived from tropos-biphenols and unusual solvent systems are the key to the selectivity observed.Entities:
Keywords: enantioselective catalysis; fluorinated solvents; hydroformylation; phosphorus ligands; rhodium
Year: 2019 PMID： 30561885 DOI： 10.1002/anie.201811888
Source DB: PubMed Journal: Angew Chem Int Ed Engl ISSN： 1433-7851 Impact factor: 15.336